Synthesis of LiNi1/3Co1/3Mn1/3O2 Cathode Material by Eutectic Molten Salt LiOH-Li2CO3

被引：0
作者：
Chang Zhaorong [1 ]
Zhang Xinkuan [2 ]
Chen Zhongjun [1 ]
Tang Hongwei [1 ]
机构：
[1] Henan Normal Univ, Xinxiang 453007, Peoples R China
[2] Xinxiang Coll, Xinxiang 453007, Peoples R China
来源：
RARE METAL MATERIALS AND ENGINEERING | 2009年 / 38卷
关键词：
Eutectic molten salt; cathode material; lithium battery; Li(Ni1/3Co1/3Mn1/3)O-2; LITHIUM-ION BATTERIES; HIGH TAP-DENSITY; ELECTROCHEMICAL CHARACTERIZATION; PERFORMANCE; COPRECIPITATION; ELECTROLYTE; DIFFRACTION;
D O I：
暂无
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
The powder of Li(Ni1/3Co1/3Mn1/3)O-2 was prepared directly without artificial grinding by a eutectic molten-salt mixture(0.24LiCO(3)-0.76LiOH with a melting point of 423 degrees C) method, where the ratio of Li/(Ni+Co+Mn) in the raw materials of Ni1/3Co1/3Mn1/3(OH)(2) and eutectic molten salt was controlled at 1:1. According to this method, the eutectic molten-salt mixture was self-mixed with precursor, and then sintered at a certain temperature. The tap-density of the powder obtained was 2.89 g.cm(-3). The well-layered alpha-NaFeO(2)structure and regular morphology were confirmed by X-ray diffraction (XRD) and scanning electron microscopy (SEM). Cathodic behaviour was examined by charge-discharge cycling, The synthesized powder showed initial charge-discharge capacity of 176 mAh.g(-1) and 166 mAh.g(-1) up to 50 cycles with no noticeable capacity-fading.
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页码：29 / 32
页数：4
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