Synthesis of LiNi1/3Co1/3Mn1/3O2 Cathode Material by Eutectic Molten Salt LiOH-Li2CO3

被引：0

作者：

Chang Zhaorong ^{[1
]}

Zhang Xinkuan ^{[2
]}

Chen Zhongjun ^{[1
]}

Tang Hongwei ^{[1
]}

机构：

[1] Henan Normal Univ, Xinxiang 453007, Peoples R China

[2] Xinxiang Coll, Xinxiang 453007, Peoples R China

来源：

RARE METAL MATERIALS AND ENGINEERING | 2009年 / 38卷

关键词：

Eutectic molten salt; cathode material; lithium battery; Li(Ni1/3Co1/3Mn1/3)O-2; LITHIUM-ION BATTERIES; HIGH TAP-DENSITY; ELECTROCHEMICAL CHARACTERIZATION; PERFORMANCE; COPRECIPITATION; ELECTROLYTE; DIFFRACTION;

D O I：

暂无

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The powder of Li(Ni1/3Co1/3Mn1/3)O-2 was prepared directly without artificial grinding by a eutectic molten-salt mixture(0.24LiCO(3)-0.76LiOH with a melting point of 423 degrees C) method, where the ratio of Li/(Ni+Co+Mn) in the raw materials of Ni1/3Co1/3Mn1/3(OH)(2) and eutectic molten salt was controlled at 1:1. According to this method, the eutectic molten-salt mixture was self-mixed with precursor, and then sintered at a certain temperature. The tap-density of the powder obtained was 2.89 g.cm(-3). The well-layered alpha-NaFeO(2)structure and regular morphology were confirmed by X-ray diffraction (XRD) and scanning electron microscopy (SEM). Cathodic behaviour was examined by charge-discharge cycling, The synthesized powder showed initial charge-discharge capacity of 176 mAh.g(-1) and 166 mAh.g(-1) up to 50 cycles with no noticeable capacity-fading.

引用

页码：29 / 32

页数：4

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[1] Shape optimization of one-chamber cross-flow mufflers by GA optimization [J].