Synthesis, characterization and investigation of the electrochemical hydrogen storage properties of CuO CeO2 nanocomposites synthesized by green method

被引：67

作者：

Sangsefidi, Fatemeh Sadat ^{[1
]}

Salavati-Niasari, Masoud ^{[1
]}

Khojasteh, Hossein ^{[1
]}

Shabani-Nooshabadi, Mehdi ^{[1
]}

机构：

[1] Univ Kashan, Inst Nano Sci & Nano Technol, POB 87317-51167, Kashan, Iran

来源：

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2017年 / 42卷 / 21期

基金：

美国国家科学基金会;

关键词：

CuO-CeO2; Nanostructures; Thermal decomposition; Hydrogen storage; Optical property; TEMPERATURE CO OXIDATION; SELECTIVE OXIDATION; HYDROTHERMAL SYNTHESIS; CATALYTIC-PROPERTIES; CARBON NANOTUBES; METAL-OXIDES; CERIA; NANOSTRUCTURES; NANOPARTICLES; COMBUSTION;

D O I：

10.1016/j.ijhydene.2017.04.103

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Pure CuO-Ce02 nanocomposites were synthesized by simple thermal decomposition method in presence of various Cu salts as a copper source and fructose as a green capping agent. In this study, the effect of various parameters such as the type of copper sources, temperature and time of reaction on the morphology and the particles size were studied. The products were characterized via X-ray diffraction (XRD) pattern, scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDX), transmission electron microscopy (TEM), N2 adsorption (BET), vibrating sample magnetometer (VSM), and infrared spectrum (FT-IR). The optical property of the nanocomposite was examined via UV vis (DRS) spectroscopy and the band gap was calculated to 3 eV. Also, the hydrogen storage capacity of CuO-CeO2 nanocomposites and CeO2 nanoparticles were investigated via chronopotentiometry method for the first time. The discharge capacity of CeO2 nano particles and CuO-CeO2 nanocomposites in 1 mA current and 20 cycles obtained 2150 and 2450 mAh/g, respectively. (C) 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.

引用

页码：14608 / 14620

页数：13

共 49 条

[1] Inhibition of Neuroblastoma cancer cells viability by ferromagnetic Mn doped CeO2 monodisperse nanoparticles mediated through reactive oxygen species [J].

Abbas, Fazal ;

Jan, Tariq ;

Iqbal, Javed ;

Naqvi, M. Sajjad Haider ;

Ahmad, Ishaq .

MATERIALS CHEMISTRY AND PHYSICS, 2016, 173 :146-151

[2] Differential cytotoxicity of ferromagnetic Co doped CeO2 nanoparticles against human neuroblastoma cancer cells [J].

Abbas, Fazal ;

Iqbal, J. ;

Jan, T. ;

Naqvi, M. Sajjad H. ;

Gul, Asma ;

Abbasi, Rashda ;

Mahmood, Arshad ;

Ahmad, Ishaq ;

Ismail, M. .

JOURNAL OF ALLOYS AND COMPOUNDS, 2015, 648 :1060-1066

[3] Effect of Mn doping on the structural, magnetic, optical and electrical properties of ZrO2-SnO2 thin films prepared by solegel method [J].

Anitha, V. S. ;

Lekshmy, S. Sujatha ;

Joy, K. .

JOURNAL OF ALLOYS AND COMPOUNDS, 2016, 675 :331-340

[4] Green synthesis of magnetic chitosan nanocomposites by a new sol-gel auto-combustion method [J].

Ansari, Fatemeh ;

Sobhani, Azam ;

Salavati-Niasari, Masoud .

JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2016, 410 :27-33

[5] Composite polymer core-ceria shell abrasive particles during oxide CMP: A defectivity study [J].

Armini, S. ;

De Messemaeker, J. ;

Whelan, C. M. ;

Moinpour, M. ;

Maex, K. .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2008, 155 (09) :H653-H660

[6] Oxidase-Like Activity of Polymer-Coated Cerium Oxide Nanoparticles [J].

Asati, Atul ;

Santra, Santimukul ;

Kaittanis, Charalambos ;

Nath, Sudip ;

Perez, J. Manuel .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (13) :2308-2312

[7] Influence of the preparation method on the performance of CuO-CeO2 catalysts for the selective oxidation of CO [J].

Avgouropoulos, G ;

Ioannides, T ;

Matralis, H .

APPLIED CATALYSIS B-ENVIRONMENTAL, 2005, 56 (1-2) :87-93

[8] CuO-CeO2 mixed oxide catalysts for the selective oxidation of carbon monoxide in excess hydrogen [J].

Avgouropoulos, G ;

Ioannides, T ;

Matralis, HK ;

Batista, J ;

Hocevar, S .

CATALYSIS LETTERS, 2001, 73 (01) :33-40

[9] Co2SiO4 nanostructures: New simple synthesis, characterization and investigation of optical property [J].

Bayat, Shima ;

Sobhani, Azam ;

Salavati-Niasari, Masoud .

MATERIALS RESEARCH BULLETIN, 2017, 88 :248-257

[10] OXYGEN GAS SENSORS BASED ON CEO2 THICK AND THIN-FILMS [J].

BEIE, HJ ;

GNORICH, A .

SENSORS AND ACTUATORS B-CHEMICAL, 1991, 4 (3-4) :393-399

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