Preservation of chemical residue-melt equilibria in natural anatexite: the effects of deformation and rapid cooling

A combined petrologic, textural and chemical approach is used to interpret the relationship between chemical exchange and deformation during partial melting of a granodioritic gneiss in the contact aureole of the Bergell Pluton (Central Alps). In contrast to most regional metamorphic anatexites, chemical equilibrium between residue and segregated melt was attained and preserved by several elements, as shown by their present distribution. Equilibrium involved both the major and the trace elements hosted in the rock-forming minerals and the light rare earth elements (LREE), hosted primarily in allanite. Equilibrium with respect to LREEs was achieved because allanite had a reactive behaviour during water-present melting, in contrast to the refractive behaviour of xenotime, which mostly controls the distribution of the HREE's. The attainmenfffft and preservation of equilibrium between leucosome and residue requires peculiar boundary conditions. We propose that the achievement of equilibrium between melt and residue was promoted by deformation, operating via a mechanism of melt present granular flow (i.e. dissolution-accommodated grain-boundary sliding active during partial melting). Microstructural observations indicate that melt-present granular flow was the dominating deformation mechanism in these anatexites. The preservation of residue-melt equilibrium is inferred to result from rapid cooling under contact metamorphic conditions and from the lack of deformation below the solidus.