Theoretical studies of rotational barriers of vinylidene ligands in the five-coordinate complexes M(X)Cl(=C=CHR)L2 (M = Os, Ru; L = phosphine)

被引：17

作者：

Yang, SY ^{[1
]}

Wen, TB ^{[1
]}

Jia, GC ^{[1
]}

Lin, ZY ^{[1
]}

机构：

[1] Hong Kong Univ Sci & Technol, Dept Chem, Hong Kong, Peoples R China

来源：

ORGANOMETALLICS | 2000年 / 19卷 / 25期

关键词：

D O I：

10.1021/om000491w

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Rotational barriers of vinylidene ligands in the five-coordinate complexes M(X)Cl(=C=CHR)L-2 (M = Os, Ru; L = phosphine) have been investigated by density functional theory calculations at the level of B3LYP. The effects of ligand X, transition metal M, and substituent R on the barriers have been examined. The results show that the rotational barriers increase with X from having pi -acceptor, sigma -donor to having pi -donor properties. Ligands (X) with pi -acceptor properties stabilize the transition state structures through interactions with the d orbital used for metal-vinylidene pi bonding in the most stable conformations and, therefore, give smaller rotational barriers. Studies of the influence of different substituents R show that the rotational barriers also increase with the electron donation abilities of R. The rotational barriers for Os complexes are generally higher in comparison to those of the Ru analogues. This result is related to the stronger osmium-ligand interactions because of the more diffuse d orbitals of the heavier metal.

引用

页码：5477 / 5483

页数：7

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