The reaction pathway of Ti-SiC system in Cu melts

被引:15
作者
Ding, Haimin [1 ]
Miao, Wenzhi [1 ]
Chu, Weiwen [1 ]
Liu, Qing [1 ]
Wang, Jinfeng [1 ]
Chu, Kaiyu [1 ]
Glandut, Nicolas [2 ]
Li, Chong [3 ]
机构
[1] North China Elect Power Univ, Sch Energy Power & Mech Engn, Baoding 071003, Peoples R China
[2] Univ Limoges, European Ceram Ctr, CNRS, IRCER,UMR 7315, 12 Rue Atlantis, F-87068 Limoges, France
[3] Tianjin Univ, Sch Mat Sci & Engn, Tianjin 300350, Peoples R China
关键词
Carbides; Carbon; Reaction pathway; TiC; SiC; SOLID-STATE REACTION; MECHANICAL-PROPERTIES; MICROSTRUCTURE EVOLUTION; POWDER-METALLURGY; F/SIC COMPOSITES; SILICON-CARBIDE; TITANIUM; BEHAVIOR; MORPHOLOGY; CERAMICS;
D O I
10.1016/j.jallcom.2019.152860
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this work, the initial stage of Ti-SiC reaction in the Cu melts has been verified. It is proved that there are two alternative Ti-SiC reaction path ways which will make SiC firstly transform into TiC or carbon derived from silicon carbide (CDC), respectively. Although TiC is more thermally favorable than both SiC and CDC in Cu melts, which means that TiC should be the ultimate C-containing product of Ti-SiC reaction of both reaction path ways, the presence of TiC shell can prevent the SiC or CDC from further transformation. As a result, SiC@TiC or CDC@TiC core-shell particles can be obtained. The synthesized CDC is composed of polycrystalline graphite and a hexagonal carbon (PDF 26-1083), and with the former one dominated. (C) 2019 Elsevier B.V. All rights reserved.
引用
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页数:8
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