Synthesis of unsymmetrical 2,8- and 2,9-dihalo-1,10-phenanthrolines and derivatives

被引：39

作者：

Toyota, S ^{[1
]}

Woods, CR ^{[1
]}

Benaglia, M ^{[1
]}

Siegel, JS ^{[1
]}

机构：

[1] Univ Calif San Diego, Dept Chem, La Jolla, CA 92093 USA

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 18期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0040-4039(98)00409-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A general method for the preparation of the unsymmetrical 2,8- and 2,9-dihalophenanthrolines is presented. The use of these halophenanthrolines as synthetic substrates in the Suzuki and Sonogashira/Castro-Stevens palladium catalyzed chemistry is exemplifed. These derivatized phenanthrolines are seen as key building blocks for the design and construction of topologically complex polynuclear metal coordination complexes. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：2697 / 2700

页数：4

共 25 条

[1] Inorganic arrays via multicomponent self-assembly: The spontaneous generation of ladder architectures [J].

Baxter, PNW ;

Hanan, GS ;

Lehn, JM .

CHEMICAL COMMUNICATIONS, 1996, (17) :2019-2020

[2] SUBSTITUTED 1,10-PHENANTHROLINES .4. BROMO DERIVATIVES [J].

CASE, FH .

JOURNAL OF ORGANIC CHEMISTRY, 1951, 16 (06) :941-945

[3] TRANSITION-METALS AS ASSEMBLING AND TEMPLATING SPECIES - FROM CATENANES AND KNOTS TO ORGANIZED MULTI-PORPHYRINS ARRAYS [J].

CHAMBRON, JC ;

DIETRICHBUCHECKER, CO ;

HEITZ, V ;

NIERENGARTEN, JF ;

SAUVAGE, JP ;

PASCARD, C ;

GUILHEM, J .

PURE AND APPLIED CHEMISTRY, 1995, 67 (02) :233-240

[4]

CHENG CC, 1982, ORG REACTIONS, V28, P37

[5] HIGH-YIELD SYNTHESIS OF A DICOPPER(I) TREFOIL KNOT CONTAINING 1,3-PHENYLENE GROUPS AS BRIDGES BETWEEN THE CHELATE UNITS [J].

DIETRICHBUCHECKER, CO ;

SAUVAGE, JP ;

DECIAN, A ;

FISCHER, J .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (19) :2231-2232

[6] DIRECT SYNTHESIS OF DISUBSTITUTED AROMATIC POLYIMINE CHELATES [J].

DIETRICHBUCHECKER, CO ;

MARNOT, PA ;

SAUVAGE, JP .

TETRAHEDRON LETTERS, 1982, 23 (50) :5291-5294

[7]

Farina V., 1995, COMPREHENSIVE ORGANO, V12, P161

[8] Self-assembly of a circular double helicate [J].

Hasenknopf, B ;

Lehn, JM ;

Kneisel, BO ;

Baum, G ;

Fenske, D .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1996, 35 (16) :1838-1840

[9]

HECK RF, 1985, PALLADIUM ASSISTED C

[10]

Katritzky A. R., 1990, ADV HETEROCYCLIC CHE, V47

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