A novel two-dimensional rectangular network.: Synthesis and structure of {[Cu(4,4′-bpy)(pyz)(H2O)2][PF6]2}n (4,4′-bpy equals 4,4′-bipyridine, pyz equals pyrazine)

被引：166
作者：
Tong, ML
Chen, XM [1 ]
Yu, XL
Mak, TCW
机构：
[1] Zhongshan Univ, Dept Chem, Guangzhou 510275, Peoples R China
[2] Chinese Univ Hong Kong, Dept Chem, Shatin, New Territories, Hong Kong
来源：
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1998年 / 01期
关键词：
D O I：
10.1039/a706363f
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The complex {[Cu(4,4'-bpy)(pyz)(H2O)(2)][PF6](2)}. comprising two-dimensional rectangular grids with each cavity enclosed by two 4,4'-bipyridine (4,4'-bipy) and two pyrazine (pyz) ligands, which superpose in an off-set fashion to give smaller rectangular channels, has been prepared and characterized by single-crystal X-ray structural analysis.
引用
收藏
页码：5 / 6
页数：2
相关论文
共 23 条
[11]   ZEOLITES - CATALYSTS FOR ORGANIC SYNTHESES [J].
HOLDERICH, W ;
HESSE, M ;
NAUMANN, F .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1988, 27 (02) :226-246
[12]  
Johnson C. K., 1976, ORNL5138 ORTEP
[13]  
KAWATA S, 1994, ANGEW CHEM INT EDIT, V33, P1759, DOI 10.1002/anie.199417591
[14]   Crystal structure of a flexible self-assembled two-dimensional square network complex [Cu-2(C3H2O4)(2)(H2O)(2)(4,4'-bpy)]center dot H2O [J].
Li, JM ;
Zeng, HQ ;
Chen, JH ;
Wang, QM ;
Wu, XT .
CHEMICAL COMMUNICATIONS, 1997, (13) :1213-1214
[15]   A noninterpenetrated molecular ladder with hydrophobic cavities [J].
Losier, P ;
Zaworotko, MJ .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1996, 35 (23-24) :2779-2782
[16]  
ROBIN R, 1992, SUPRAMOLECULAR ARCHI, P256
[17]  
Sheldrick G., 1990, SHELXTL PC USERS MAN
[18]  
SHELDRICK GM, 1993, SHELXL 93 PROGRAM XR
[19]   Self-assembly of luminescent molecular squares featuring octahedral rhenium corners [J].
Slone, RV ;
Hupp, JT ;
Stern, CL ;
AlbrechtSchmitt, TE .
INORGANIC CHEMISTRY, 1996, 35 (14) :4096-&
[20]  
SOMA T, 1994, ANGEW CHEM INT EDIT, V33, P1665, DOI 10.1002/anie.199416651
123