High-field (high-frequency) EPR spectroscopy and structural characterization of a novel manganese(III) corrole

被引：84
作者：
Bendix, J
Gray, HB [1 ]
Golubkov, G
Gross, Z
机构：
[1] CALTECH, Beckman Inst, Pasadena, CA 91125 USA
[2] Technion Israel Inst Technol, Dept Chem, IL-32000 Haifa, Israel
[3] Technion Israel Inst Technol, Inst Catalysis Sci & Technol, IL-32000 Haifa, Israel
来源：
CHEMICAL COMMUNICATIONS | 2000年 / 19期
关键词：
D O I：
10.1039/b006299p
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The X-ray structure, magnetic susceptibility, and high-field (high-frequency) EPR spectrum of manganese 5,10,15-tris(pentafluorophenyl) corrole unambiguously establish that the complex contains an isolated, slightly rhombic, manganese(III) center.
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页码：1957 / 1958
页数：2
相关论文
共 24 条
[1]  
[Anonymous], CYTOCHROME P 450
[2]   Electronic structure of manganese(III) compounds from high-frequency EPR spectra [J].
Barra, AL ;
Gatteschi, D ;
Sessoli, R ;
Abbati, GL ;
Cornia, A ;
Fabretti, AC ;
Uytterhoeven, MG .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (21) :2329-2331
[3]  
BENDIX J, 2000, IN PRESS ANGEW CHEM, V39
[4]  
Erben C., 2000, PORPHYRIN HDB, V2, P233
[5]   MAGNETIC-SUSCEPTIBILITY AND EPR-SPECTRA OF MU-CYANO-BIS[PENTAAMMINECHROMIUM(III)] PERCHLORATE [J].
GLERUP, J ;
WEIHE, H .
ACTA CHEMICA SCANDINAVICA, 1991, 45 (05) :444-448
[6]   EPR spectra from ''EPR-silent'' species: High-field EPR spectroscopy of manganese(III) porphyrins [J].
Goldberg, DP ;
Telser, J ;
Krzystek, J ;
Montalban, AG ;
Brunel, LC ;
Barrett, AGM ;
Hoffman, BM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (37) :8722-8723
[7]   Halogen to metal π-donation in metalloporphyrins [J].
Gross, Z ;
Mahammed, A ;
Barzilay, CM .
CHEMICAL COMMUNICATIONS, 1998, (10) :1105-1106
[8]   First catalysis by corrole metal complexes: epoxidation, hydroxylation, and cyclopropanation [J].
Gross, Z ;
Simkhovich, L ;
Galili, N .
CHEMICAL COMMUNICATIONS, 1999, (07) :599-600
[9]   Solvent-free condensation of pyrrole and pentafluorobenzaldehyde:: A novel synthetic pathway to corrole and oligopyrromethenes [J].
Gross, Z ;
Galili, N ;
Simkhovich, L ;
Saltsman, I ;
Botoshansky, M ;
Bläser, D ;
Boese, R ;
Goldberg, I .
ORGANIC LETTERS, 1999, 1 (04) :599-602
[10]  
Gross Z, 1999, ANGEW CHEM INT EDIT, V38, P1427, DOI 10.1002/(SICI)1521-3773(19990517)38:10<1427::AID-ANIE1427>3.0.CO
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