High-field (high-frequency) EPR spectroscopy and structural characterization of a novel manganese(III) corrole

被引:85
作者
Bendix, J
Gray, HB [1 ]
Golubkov, G
Gross, Z
机构
[1] CALTECH, Beckman Inst, Pasadena, CA 91125 USA
[2] Technion Israel Inst Technol, Dept Chem, IL-32000 Haifa, Israel
[3] Technion Israel Inst Technol, Inst Catalysis Sci & Technol, IL-32000 Haifa, Israel
关键词
D O I
10.1039/b006299p
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The X-ray structure, magnetic susceptibility, and high-field (high-frequency) EPR spectrum of manganese 5,10,15-tris(pentafluorophenyl) corrole unambiguously establish that the complex contains an isolated, slightly rhombic, manganese(III) center.
引用
收藏
页码:1957 / 1958
页数:2
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