Transition metal catalyzed oxidation, 10 - Zirconium-catalyzed oxidation of primary aliphatic amines to nitro compounds with tert-butyl hydroperoxide

被引：0
作者：
Krohn, K [1 ]
Kupke, J [1 ]
机构：
[1] Univ Gesamthsch Paderborn, Fachbereich Chem & Chem Tech, D-33098 Paderborn, Germany
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 1998年 / 1998卷 / 04期
关键词：
aliphatic amines; aliphatic nitro compounds; oxidation; zirconium tetra-tert-butylate; tert-butyl hydroperoxide;
D O I：
10.1002/(SICI)1099-0690(199804)1998:4<679::AID-EJOC679>3.0.CO;2-W
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Primary aliphatic amines are oxidized with tert-butyl hydroperoxide to the corresponding nitro compounds in 50-98% yield using Zr(Ot-Bu)(4) as the catalyst. The CH-acidic nitro compounds are not epimerized under these reaction conditions.
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页码：679 / 682
页数：4
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