A novel poly(o-anisidine)/CoFe2O4 multifunctional nanocomposite: Preparation, characterization and properties

被引:27
作者
Jiang, Jing [1 ]
Ai, Lun-Hong [1 ]
Liu, Ai-Hua [1 ]
机构
[1] China W Normal Univ, Key Lab Chem Synth & Pollut Control Sichuan Prov, Coll Chem & Chem Engn, Nanchong 637002, Peoples R China
关键词
Conducting polymers; CoFe2O4; Structural characterization; Properties; FERRITE NANOPARTICLES; MAGNETIC-PROPERTIES; NANOCRYSTALLINE; POLYANILINE; POLYMERIZATION; COMPOSITES;
D O I
10.1016/j.synthmet.2009.10.032
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A novel poly(o-anisidine) (POA)/CoFe2O4 nanocomposite was synthesized by a facile in situ polymerization of o-anisidine in the presence of CoFe2O4 nanoparticles which were obtained by a simple refluxing process in ethylene glycol. The structures of the resulting nanocomposite were investigated by means of X-ray diffraction (XRD) and Fourier transform infrared (FTIR) spectra. The optical, thermal and magnetic properties of the POA/CoFe2O4 nanocomposite were characterized by UV-visible spectrometer, thermogravimetry analyzer (TGA) and vibrating sample magnetometer (VSM). It was indicated the existence of CoFe2O4 in the POA/CoFe2O4 nanocomposite. The scanning electron microscopy (SEM) observation illustrated that POA layers were wrapped on the surface of CoFe2O4 nanoparticles appearing as small aggregated globules. The POA/CoFe2O4 nanocomposite exhibited a ferromagnetic behavior under applied magnetic field at room temperature. The saturation magnetization of POA/CoFe2O4 nanocomposite was lower than that of pure CoFe2O4 nanoparticles due to the contribution of non-magnetic POA layers. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:333 / 336
页数:4
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