Reductive Silylation of the Uranyl Ion with Ph3SiOTf

被引：18

作者：

Pedrick, Elizabeth A. ^{[1
]}

Wu, Guang ^{[1
]}

Hayton, Trevor W. ^{[1
]}

机构：

[1] Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA

来源：

INORGANIC CHEMISTRY | 2014年 / 53卷 / 23期

基金：

美国国家科学基金会;

关键词：

OXO-GROUP SILYLATION; BOND FORMATION; COMPLEXES; URANIUM; SILICON; SALTS;

D O I：

10.1021/ic502267t

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of 2 equiv of Ph3SiOTf with UO2(dbm)(2)(THF) (dbm = OC(Ph)CHC(Ph)O) and UO2((Ar)acnac)(2) ((Ar)acnac = ArNC(Ph)CHC(Ph)O; Ar = 3,5-(t)Bu2C6H3) results in the formation of U(OSiPh3)(2)(dbm)(2)(OTf) (1) and [U(OSiPh3)2((Ar)acnac)(2)][OTf](2)), respectively, in good yield.

引用

页码：12237 / 12239

页数：3

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