Facile Fabrication of ZnO/TiO2 Heterogeneous Nanofibres and Their Photocatalytic Behaviour and Mechanism towards Rhodamine B

被引:41
作者
Chen, JiaDong [1 ]
Liao, WeiSha [1 ]
Jiang, Ying [1 ]
Yu, DanNi [1 ]
Zou, MeiLing [1 ]
Zhu, Han [1 ]
Zhang, Ming [1 ]
Du, MingLiang [1 ]
机构
[1] Zhejiang Sci Tech Univ, Coll Mat & Text, Dept Mat Engn, Hangzhou, Zhejiang, Peoples R China
关键词
Nanofibres; Photocatalytic Activities; Zinc Oxide; Titanium Dioxide; Rhodamine B; TIO2; PARTICLES; AZO-DYE; NANOCOMPOSITES; DEGRADATION; ORANGE; PHOTODEGRADATION; NANOPARTICLES; KINETICS; SURFACE;
D O I
10.5772/62291
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
In this study, novel titanium dioxide (TiO2) and zinc oxide (ZnO) hybrid photocatalysts in the form of nanofibres were fabricated by a facile method using electrospinning followed by a calcination process. Scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) were employed to investigate the morphology and structure of the heterogeneous nanofibres. The photocatalytic performances were evaluated via the photodegradation of Rhodamine B (RhB) under irradiation with UV light. Due to the low recombination rate of photo-induced charge carriers, the high utilization efficiency of UV light and the large contact area with the target molecules, the ZnO/TiO2 hybrid nanofibres exhibited high catalytic activity towards the Rhodamine B, and the amount of Zn(OAc)(2) in the precursor of these nanofibres played an important role in determining the photo decomposition performance.
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页数:8
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共 34 条
[1]   Aqueous synthesis and enhanced photocatalytic activity of ZnO/Fe2O3 heterostructures [J].
Achouri, Faouzi ;
Corbel, Serge ;
Aboulaich, Abdelhay ;
Balan, Lavinia ;
Ghrabi, Ahmed ;
Ben Said, Myriam ;
Schneider, Raphael .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2014, 75 (10) :1081-1087
[2]   Heterogeneous photocatalytic treatment of simulated dyehouse effluents using novel TiO2-photocatalysts [J].
Arslan, I ;
Balcioglu, IA ;
Bahnemann, DW .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2000, 26 (03) :193-206
[3]   Elaboration of pure and doped TiO2 nanoparticles in sol-gel reactor with turbulent micromixing: Application to nanocoatings and photocatalysis [J].
Azouani, R. ;
Michau, A. ;
Hassouni, K. ;
Chhor, K. ;
Bocquet, J. -F. ;
Vignes, J. -L. ;
Kanaev, A. .
CHEMICAL ENGINEERING RESEARCH & DESIGN, 2010, 88 (9A) :1123-1130
[4]   Experimental and numerical investigation of nanoparticle removal using acoustic streaming and the effect of time [J].
Bakhtari, Kaveh ;
Guldiken, Rasim O. ;
Makaram, Prashanth ;
Busnaina, Ahmed A. ;
Park, Jin-Goo .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2006, 153 (09) :G846-G850
[5]   Alignment of colloidal CdS nanowires embedded in polymer nanofibers by electrospinning [J].
Bashouti, M ;
Salalha, W ;
Brumer, M ;
Zussman, E ;
Lifshitz, E .
CHEMPHYSCHEM, 2006, 7 (01) :102-106
[6]   Photooxidation of an azo dye induced by visible light incident on the surface of TiO2 [J].
Bauer, C ;
Jacques, P ;
Kalt, A .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2001, 140 (01) :87-92
[7]   Photoinduced reactivity of titanium dioxide [J].
Carp, O ;
Huisman, CL ;
Reller, A .
PROGRESS IN SOLID STATE CHEMISTRY, 2004, 32 (1-2) :33-177
[8]   Photocatalytic Comparison of TiO2 Nanoparticles and Electrospun TiO2 Nanofibers: Effects of Mesoporosity and Interparticle Charge Transfer [J].
Choi, Sung Kyu ;
Kim, Soonhyun ;
Lim, Sang Kyoo ;
Park, Hyunwoong .
JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (39) :16475-16480
[9]   TiO2-ITO and TiO2-ZnO nanocomposites: application on water treatment [J].
Chorfi, H. ;
Saadoun, M. ;
Bousselmi, L. ;
Bessais, B. .
EMM-FM2011 - FIRST EURO MEDITERRANEAN MEETING ON FUNCTIONALIZED MATERIALS, 2012, 29
[10]   Band structures and nitrogen doping effects in zinc titanate photocatalysts [J].
Conesa, Jose C. .
CATALYSIS TODAY, 2013, 208 :11-18