Luminescence characteristics of the Rb2CdI4 crystal

被引:0
作者
Berdychevsky, OM [1 ]
Vistovsky, VV [1 ]
Pidzyrailo, MS [1 ]
Bolesta, IM [1 ]
Storchun, MV [1 ]
机构
[1] Ivan Franko Lviv Natl Univ, Dept Phys, UA-79005 Lviv, Ukraine
关键词
crystal; exciton; emission spectrum; reflection spectrum;
D O I
10.1016/S0030-4018(00)00931-7
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Optical reflection spectra of Rb2CdI4 single crystals were measured in the region of exciton creation at temperatures 77-250 K. Band gap width (E-g = 4.927 eV), binding energy (F = 0.390 eV) and radius (r(ex) = 4.43 Angstrom) of excitons were determined. Emission spectra at excitation in the exciton absorption bands and at band-to-band transitions were studied in the temperature region 8-300 K. The pi- and sigma-emission bands of the self-trapped exciton have observed at 3.06 and 3.44 eV, respectively. The temperature dependencies of intensities of excitation bands of Mn2+ centres in the region of intrinsic absorption give evidence of the existence of two additional bands, connected with the localization of excitons near impurity centres. (C) 2000 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:169 / 174
页数:6
相关论文
共 10 条
  • [1] Agranovich V.M., 1968, Theory of Excitons
  • [2] Band energy structure and optical spectra of Cs2CdI4 crystals
    Bolesta, I
    Furgala, Y
    Kityk, I
    Velgosh, S
    [J]. FERROELECTRICS LETTERS SECTION, 1996, 21 (5-6) : 175 - 178
  • [3] Bolesta I.M., 1991, UKR FIZ ZH, V36, P1654
  • [4] GESI K, 1984, J PHYS SOC JPN, V53, P3850
  • [5] Lushchik Ch B, 1989, Decay of Electronic Excitations with Defect Formation in Solids
  • [6] PIDZYRAILO MS, 1999, SCINT 99 C BOOK ABST, P166
  • [7] PLEKHANOV VG, 1974, IZV AN SSSR FIZ+, V38, P1304
  • [8] EMISSION-SPECTRA OF KBR-SN-2+
    SCACCO, A
    JACOBS, PWM
    [J]. JOURNAL OF LUMINESCENCE, 1982, 26 (04) : 393 - 409
  • [9] Song K, 1993, Springer Series in Solid-State Sciences
  • [10] ZIMMERER G, 1991, NUCL INSTRUM METH A, V308, P1782