Formation of Methyl Acrylate from CO2 and Ethylene via Methylation of Nickelalactones

被引：102

作者：

Bruckmeier, Christian ^{[1
]}

Lehenmeier, Maximilian W. ^{[1
]}

Reichardt, Robert ^{[1
]}

Vagin, Sergei ^{[1
]}

Rieger, Bernhard ^{[1
]}

机构：

[1] Tech Univ Munich, WACKER Lehrstuhl Makromol Chem, D-85748 Garching, Germany

来源：

ORGANOMETALLICS | 2010年 / 29卷 / 10期

关键词：

CARBON-DIOXIDE; PALLADIUM; ALKENES; ACID; COMPLEX; TRANSFORMATION; REACTIVITY; NICKEL(0); ETHENE; WELL;

D O I：

10.1021/om100060y

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The nickel-induced coupling of ethylene and CO2 represents a promising pathway toward acrylates. To overcome the high bond dissociation energies of the M-O moieties, we worked out an in situ methylation of nickelalactones to realize the beta-hydirde elimination and the liberation of the acrylate species.

引用

页码：2199 / 2202

页数：4

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