Synthesis of self-assembled needle-shaped calcium carbonate superstructures

被引:2
|
作者
Zhao LiNa [1 ]
Feng JingDong [1 ]
Wang XiuYan [1 ]
Wang ZiChen [2 ]
机构
[1] Jilin Normal Univ, Coll Chem, Siping 136000, Peoples R China
[2] Jilin Univ, Inst Chem, Changchun 130023, Peoples R China
来源
CHINESE SCIENCE BULLETIN | 2010年 / 55卷 / 20期
关键词
calcium carbonate; self-assembled; needle-shaped; hydrophobic; MORPHOLOGICAL CONTROL; CRYSTALLIZATION; CACO3; TEMPERATURE; PARTICLES; MATRIX; GROWTH;
D O I
10.1007/s11434-010-3283-4
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Novel self-assembled calcium carbonate (CaCO3) crystals exhibiting the morphology of well-defined needles were synthesized by a simple precipitation reaction in the presence of octadecyl dihydrogen phosphate (ODP) as a crystal additive. The CaCO3 obtained by this method is hydrophobic, making it likely to be used widely in industry. The resulting products were characterized by powder X-ray diffraction, field emission scanning electron microscopy, Fourier transform infrared spectroscopy and contact angle experiments. The results indicated that ODP plays an important role in determining the structure, morphology and hydrophobicity of CaCO3 crystals.
引用
收藏
页码:2131 / 2135
页数:5
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