Pd/Ni-Catalyzed Germa-Suzuki coupling via dual Ge-F bond activation

被引：18
作者：
Kameo, Hajime [1 ]
Mushiake, Akihiro [1 ]
Isasa, Tomohito [1 ]
Matsuzaka, Hiroyuki [1 ]
Bourissou, Didier [2 ]
机构：
[1] Osaka Prefecture Univ, Grad Sch Sci, Dept Chem, Osaka 5998531, Japan
[2] Univ Paul Sabatier, Lab Heterochim Fondamentale & Appl, CNRS, UMR 5069, 118 Route Narbonne, F-31062 Toulouse 09, France
来源：
CHEMICAL COMMUNICATIONS | 2021年 / 57卷 / 41期
关键词：
RADICAL-ADDITION; Z LIGAND; COMPLEXES; CHEMISTRY; STANNANE; SILANE; FLUORINE; SILICON;
D O I：
10.1039/d1cc01392k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Pd/Ni -> Ge-F interactions supported by phosphine-chelation were found to trigger dual activation of Ge-F bonds under mild conditions. This makes fluoro germanes suitable partners for catalytic Ge-C cross-coupling and enables Germa-Suzuki reactions to be achieved for the first time.
引用
收藏
页码：5004 / 5007
页数：4
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