Allylic and benzylic oxidation using cobalt(II) alkyl phosphonate modified silica

被引：55

作者：

Jurado-Gonzalez, M ^{[1
]}

Sullivan, AC ^{[1
]}

Wilson, JRH ^{[1
]}

机构：

[1] Univ London Queen Mary Coll, Dept Chem, London E1 4NS, England

来源：

TETRAHEDRON LETTERS | 2003年 / 44卷 / 22期

基金：

英国工程与自然科学研究理事会;

关键词：

benzylic; oxidation; steroids; cobalt; phosphonate; silica; immobilised reagents;

D O I：

10.1016/S0040-4039(03)00833-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The allylic and benzylic oxidation of a range of substrates proceeds in good yield using catalytic quantities of cobalt(11) alkyl phosphonate modified silica and tert-butyl hydroperoxide. (C) 2003 Elsevier Science Ltd. All rights reserved.

引用

页码：4283 / 4286

页数：4

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