Highly selective and sensitive fluorescent probe for the detection of nitrite

被引：46

作者：

Gu, Biao ^{[1
]}

Huang, Liyan ^{[1
]}

Hu, Jiali ^{[1
]}

Liu, Jingjing ^{[1
]}

Su, Wei ^{[1
]}

Duan, Xiaoli ^{[1
]}

Li, Haitao ^{[1
]}

Yao, Shouzhuo ^{[1
]}

机构：

[1] Hunan Normal Univ, Key Lab Chem Biol & Tradit Chinese Med Res, Coll Chem & Chem Engn, Minist Educ, Changsha 410081, Hunan, Peoples R China

来源：

TALANTA | 2016年 / 152卷

基金：

中国国家自然科学基金;

关键词：

Nitrite; Fluorescent probe; Highly selective response; SPECTROFLUOROMETRIC DETERMINATION; NATURAL-WATER; HYDROGEN-SULFIDE; TRACE NITRITE; NITRATE; OXIDE; CYSTEINE; PRODUCTS; CYANIDE; FOOD;

D O I：

10.1016/j.talanta.2016.01.059

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A simple and reliable fluorescent nitrite (NO2-) probe, 2-(1H-phenanthro[9,10-d] imidazol-2-yl)aniline (PA), was rationally developed based on a novel NO2--mediated diazozation and subsequent cyclization. The new sensing mechanism of the probe was confirmed by using NMR, IR spectra, control experiments and DFT calculations. The synthesized probe showed low pH dependence, fast and highly selective fluorescence response to NO2- over other species. Under the optimized conditions, the linear response of the probe toward NO2- was in the range of 0.1-10 mu M with a low detection limit of 4.3 x 10(-8) M. Moreover, PA was successfully applied for the determination of NO2- in environmental samples and food products. (C) 2016 Elsevier B.V. All rights reserved.

引用

页码：155 / 161

页数：7

共 52 条

[1] Efficient Reaction Based Colorimetric Probe for Sensitive Detection, Quantification, and On-Site Analysis of Nitrite Ions in Natural Water Resources [J].

Adarsh, Nagappanpillai ;

Shanmugasundaram, Madhesh ;

Ramaiah, Danaboyina .

ANALYTICAL CHEMISTRY, 2013, 85 (21) :10008-10012

[2] A ratiometric fluorescence probe for selective visual sensing of Zn2+ [J].

Ajayaghosh, A ;

Carol, P ;

Sreejith, S .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (43) :14962-14963

[3] Hemilabile coordination complexes for sensing applications [J].

Angell, Sarah E. ;

Rogers, Cerrie W. ;

Zhang, Yan ;

Wolf, Michael O. ;

Jones, Wayne E., Jr. .

COORDINATION CHEMISTRY REVIEWS, 2006, 250 (13-14) :1829-1841

[4] Turn-on fluorescent probes for nitric oxide sensing based on the ortho-hydroxyamino structure showing no interference with dehydroascorbic acid [J].

Beltran, Alicia ;

Isabel Burguete, M. ;

Abanades, Daniel R. ;

Perez-Sala, Dolores ;

Luis, Santiago V. ;

Galindo, Francisco .

CHEMICAL COMMUNICATIONS, 2014, 50 (27) :3579-3581

[5] Dietary nitrites and nitrates, nitrosatable drugs, and neural tube defects [J].

Brender, JD ;

Olive, JM ;

Felkner, M ;

Suarez, L ;

Marckwardt, W ;

Hendricks, KA .

EPIDEMIOLOGY, 2004, 15 (03) :330-336

[6] Agricultural contamination of groundwater as a possible risk factor for growth restriction or prematurity [J].

Bukowski, J ;

Somers, G ;

Bryanton, J .

JOURNAL OF OCCUPATIONAL AND ENVIRONMENTAL MEDICINE, 2001, 43 (04) :377-383

[7] Heme-iron in lipid oxidation [J].

Carlsen, CU ;

Moller, JKS ;

Skibsted, LH .

COORDINATION CHEMISTRY REVIEWS, 2005, 249 (3-4) :485-498

[8] Amine functionalized tetraphenylethylene: a novel aggregation-induced emission based fluorescent chemodosimeter for nitrite and nitrate ions [J].

Chatterjee, Amrita ;

Khandare, Dipratn G. ;

Saini, Praveen ;

Chattopadhyay, Anjan ;

Majik, Mahesh S. ;

Banerjee, Mainak .

RSC ADVANCES, 2015, 5 (40) :31479-31484

[9] Colorimetric Nitrite and Nitrate Detection with Gold Nanoparticle Probes and Kinetic End Points [J].

Daniel, Weston L. ;

Han, Min Su ;

Lee, Jae-Seung ;

Mirkin, Chad A. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (18) :6362-+

[10] GAS CHROMATOGRAPHIC DETERMINATION AND MASS SPECTROMETRIC CONFIRMATION OF N-NITROSODIMETHYLAMINE IN SMOKE-PROCESSED MARINE FISH [J].

FAZIO, T ;

DAMICO, JN ;

HOWARD, JW ;

WHITE, RH ;

WATTS, JO .

JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 1971, 19 (02) :250-&

← 1 2 3 4 5 6 →