Synthesis and characterization of triphenylantimony(V) (O-alkyl, O-cycloalkyl and O-aryltrithiophosphates)

被引：5
|
作者：
Tripathi, UN [1 ]
Ahmad, MS [1 ]
机构：
[1] Vikram Univ, Sch Studies Chem, Ujjain 456010, Madhya Pradesh, India
来源：
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2004年 / 179卷 / 11期
关键词：
antimony; triphenylantimony (V); trithiophosphate;
D O I：
10.1080/10426500490485011
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Triphenylantimony (V) (O-alkyl, O-cycloalkyl and O-aryltrithiophosphates) of the type Ph3Sb[S-2(S)P(OR)] (R = Me, Et, Pr-n, Pr-i, Bu-n, Bu-s, Bu-i, Am-i, Ph and C.h. = cyclohexyl) have been synthesized for the first time by the reaction of triphenylantimony (V) dibromide with potassium trithiophosphates in 1:1 molar ratio in methanol. These new compounds have been characterized by elemental analysis, molecular weight determinations, and spectroscopic (IR,C-13 and P-31 NMR) stuclies. On the basis of these clala trigonal bipyramidal geonteoy has been proposed for these compounds.
引用
收藏
页码：2307 / 2313
页数：7
相关论文
共 29 条
  • [1] Synthesis, characterisation and reactivity of bismuth (III) (O-alkyl, O-cycloalkyl and O-aryltrithiophosphates)
    Tripathi, UN
    Ahmad, MS
    MAIN GROUP METAL CHEMISTRY, 2005, 28 (05) : 273 - 283
  • [2] Synthesis, characterisation and reactivity of arsenic(III) (O-alkyl,O-cycloalkyl and O-aryltrithiophosphates)
    Tripathi, UN
    Ahmad, MS
    MAIN GROUP METAL CHEMISTRY, 2004, 27 (03) : 169 - 179
  • [3] Synthesis, Characterization, and Sol-Gel Behavior of Dichlorotitanium(IV) (O-Alkyl, O-Cycloalkyl, and O-Aryl Trithiophosphates)
    Tripathi, U. N.
    Siddiqui, A.
    Safi, Mohd.
    Sharma, Nitya
    Srivastava, Neetu
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2010, 185 (09) : 1993 - 2001
  • [4] Triphenylantimony(v) catecholates and o-amidophenolates:: Reversible binding of molecular oxygen
    Cherkasov, Vladimir K.
    Abakumov, Gleb A.
    Grunova, Ekaterina V.
    Poddel'sky, Andrey I.
    Fukin, Georgy K.
    Baranov, Evgenii V.
    Kurskii, Yury V.
    Abakumova, Ludmila G.
    CHEMISTRY-A EUROPEAN JOURNAL, 2006, 12 (14) : 3916 - 3927
  • [5] Synthesis and Characterization of O,O′-Ditolyl-S-silylphosphorodithiolates
    Kumar, A.
    Kumar, K.
    Pandey, S. K.
    POLISH JOURNAL OF CHEMISTRY, 2009, 83 (12) : 2097 - 2104
  • [6] Triphenylantimony(V) o-amidophenolates with unsymmetrical N-aryl group for a reversible dioxygen binding
    Poddel'sky, Andrey I.
    Kurskii, Yury A.
    Piskunov, Alexandr V.
    Somov, Nikolay V.
    Cherkasov, Vladimir K.
    Abakumov, Gleb A.
    APPLIED ORGANOMETALLIC CHEMISTRY, 2011, 25 (03) : 180 - 189
  • [7] Triethylantimony(V) complexes with bidentate O,N-, O,O- and tridentate O,N,O′-coordinating o-iminoquinonato/o-quinonato ligands: Synthesis, structure and some properties
    Poddel'sky, Andrey I.
    Vavilina, Nina N.
    Somov, Nikolay V.
    Cherkasov, Vladimir K.
    Abakumov, Gleb A.
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2009, 694 (21) : 3462 - 3469
  • [8] New Organic Derivatives of O,O′-(o-, m-, and p-Ditolyl)/Dibenzyldithiophosphates: Synthesis and Characterization
    Sharma, Sangeeta
    Magotra, Suresh
    Pandey, Sushil K.
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2009, 184 (08) : 2140 - 2151
  • [9] Synthesis and characterization of bis(O,O′-diisopropylmonothiophosphato)nickel(II) adducts and molecular structures of bis(pyridine)bis(O,O′-diisopropylmonothiophosphato)nickel(II) complex
    Bajia, Subhash C.
    Mishra, Anurag
    Butcher, Ray J.
    TRANSITION METAL CHEMISTRY, 2011, 36 (03) : 325 - 329
  • [10] Synthesis, spectral characterization, and evaluation of antimicrobial activity of O,O-alkanediyl S-(N-phthalimidomethyl) dithiophosphates and zinc bis(O,O-alkanediyl) dithiophosphates
    Rastogi, Rupali
    Gupta, Srasti
    Tarannum, Nazia
    Agarwal, Ranu
    Butcher, R. J.
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2017, 192 (03) : 300 - 306
123