Electron collisions with CO: Elastic and vibrational excitation cross sections

被引:45
作者
Allan, M. [1 ]
机构
[1] Univ Fribourg, Dept Chem, CH-1700 Fribourg, Switzerland
来源
PHYSICAL REVIEW A | 2010年 / 81卷 / 04期
基金
瑞士国家科学基金会;
关键词
ROTATIONAL-EXCITATION; MOLECULE-SCATTERING; MOMENTUM-TRANSFER; IMPACT; HELIUM; STATE; ENERGIES; ATOMS; O-2; N-2;
D O I
10.1103/PhysRevA.81.042706
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Absolute differential elastic and vibrational excitation cross sections up to v = 11 were measured for CO in scattering angle ranges extending to 180 degrees at energies between 0.2 and 5 eV ( and an elastic measurement at 10 eV). The lowest angles were 0 degrees for inelastic scattering and between 5 degrees and 20 degrees for elastic scattering, depending on energy. Integral cross sections were derived by integrating under the angular distributions and compared with previous beam and swarm measurements. The sum of the integral cross sections agrees very well with the available transmission measurements of the grand total cross section, thus validating the present measurements. The present elastic differential and integral cross sections are in excellent agreement with the best available measurement [Gibson et al., J. Phys. B 29, 3197 ( 1996)], but the v = 1 inelastic cross section is about 25% higher. This could have consequences for simulations of cometary and planetary atmospheres.
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页数:9
相关论文
共 37 条
[1]   Measurement of absolute differential cross sections for vibrational excitation of O-2 by electron impact [J].
Allan, M .
JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS, 1995, 28 (23) :5163-5175
[2]   Absolute angle-differential elastic and vibrational excitation cross sections for electron collisions with tetrahydrofuran [J].
Allan, M. .
JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS, 2007, 40 (17) :3531-3544
[4]   Measurement of the elastic and v=0 → 1 differential electron-N2 cross sections over a wide angular range [J].
Allan, M .
JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS, 2005, 38 (20) :3655-3672
[5]   MEASUREMENT OF DIFFERENTIAL CROSS-SECTIONS FOR EXCITATION OF HELIUM BY ELECTRON-IMPACT WITHIN THE 1ST 4 EV ABOVE THRESHOLD [J].
ALLAN, M .
JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS, 1992, 25 (07) :1559-1575
[6]   Excitation of the 2 3S state of helium by electron impact from threshold to 24 eV:: measurements with the 'magnetic angle changer' [J].
Allan, M .
JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS, 2000, 33 (06) :L215-L220
[7]   Measurement of absolute differential cross sections for the excitation of the n=2 states of helium at 0 degrees and 180 degrees [J].
Asmis, KR ;
Allan, M .
JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS, 1997, 30 (08) :1961-1974
[8]   Electron-molecule scattering cross-sections. I. Experimental techniques and data for diatomic molecules [J].
Brunger, MJ ;
Buckman, SJ .
PHYSICS REPORTS-REVIEW SECTION OF PHYSICS LETTERS, 2002, 357 (3-5) :215-458
[9]   ELECTRON-SCATTERING FROM CO IN THE 2-PI RESONANCE REGION [J].
BUCKMAN, SJ ;
LOHMANN, B .
PHYSICAL REVIEW A, 1986, 34 (02) :1561-1563
[10]  
Campbell Laurence, 2008, PMC Physics B, V1, DOI 10.1186/1754-0429-1-3