Graphene-Based Carbocatalysts for Thermoset Polymers and for Diastereoselective and Enantioselective Organic Synthesis

被引：8

作者：

Acocella, Maria Rosaria ^{[1
]}

Guerra, Gaetano ^{[1
]}

机构：

[1] Univ Salerno, Dept Chem & Biol Adolfo Zambelli, Via Giovanni Paolo 2,132 Fisciano, Salerno, SA, Italy

来源：

CHEMCATCHEM | 2018年 / 10卷 / 11期

关键词：

diastereoselectivity; graphene oxide; nanocomposites; pi interactions; stacking interactions; SOLVENT-FREE CONDITIONS; RING-OPENING REACTIONS; OXIDIZED CARBON-BLACK; GRAPHITE OXIDE; MICHAEL ADDITION; ROOM-TEMPERATURE; EPOXY-RESINS; CATALYST; COMPOSITES; EFFICIENT;

D O I：

10.1002/cctc.201702015

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This review reports on the catalytic activity of graphene oxide (GO) and high-surface-area graphite (HSAG) for some relevant organic reactions. It is shown that the main drawbacks of graphite-based catalysts, that is, high catalyst loading and generally poor selectivity, can often be removed by operating under solvent-free conditions. Moreover, some reactions that are catalyzed by GO as well as HSAG are presented. For these reactions, stacking of the aromatic substrates with the graphitic planes plays a predominant role in the catalytic activity and the unexpected diastereoselective and enantioselective behaviors.

引用

页码：2350 / 2359

页数：10

共 65 条

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