The optical properties of ZnO sheets electrodeposited on ITO glass

被引:60
作者
Wang, Feifei
Liu, Ruibin
Pan, Anlian
Cao, Li
Cheng, Ke
Xue, Bofei
Wang, Geng
Meng, Qingbo
Li, Jinghong
Li, Qi
Wang, Yanguo
Wang, Taihong
Zou, Bingsuo
机构
[1] Chinese Acad Sci, Inst Phys, Beijing 100080, Peoples R China
[2] Hunan Univ, MicroNano Technol Res Ctr, Changsha 410082, Peoples R China
[3] Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China
基金
中国国家自然科学基金;
关键词
ZINC-OXIDE; ROOM-TEMPERATURE; ELECTROCHEMICAL GROWTH; LASER-EMISSION; SOLAR-CELLS; FILMS; DEPOSITION; ARRAYS; LIGHT; PHOTOLUMINESCENCE;
D O I
10.1016/j.matlet.2006.08.007
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Large-scale hexagonal ZnO sheets were grown on ITO glass by cathodic electrodeposition in an aqueous zinc nitrate/potassium chloride solution at 60 degrees C and annealing at 350 degrees C for an hour. The sheets are about 3 mu m in dimension and 100-300 nm in thickness. The ZnO sheets show many nano-pits on the surface and produce intense green luminescence at room temperature under femtosecond (fs) pulse ultraviolet (UV) light excitation. Both power-dependent photoluminescence spectra and time-resolved spectra were measured with varied excitation powers. Lasing phenomena occur at above 500 PJ/cm(2) and the stimulated emission occurs with lifetime of less than 30 ps over 600 mu J/cm(2). Additionally, the open-circuit photovoltage spectra indicate that the light-absorbing dye of RuL2(NCS)(2)(N3) can be well adsorbed on the surface of ZnO sheets, which is useful for the dye-sensitized solar cells(DSSC). (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:2000 / 2003
页数:4
相关论文
共 33 条
[21]   High-density, ordered ultraviolet light-emitting ZnO nanowire arrays [J].
Liu, CH ;
Zapien, JA ;
Yao, Y ;
Meng, XM ;
Lee, CS ;
Fan, SS ;
Lifshitz, Y ;
Lee, ST .
ADVANCED MATERIALS, 2003, 15 (10) :838-+
[22]   CONVERSION OF LIGHT TO ELECTRICITY BY CIS-X2BIS(2,2'-BIPYRIDYL-4,4'-DICARBOXYLATE)RUTHENIUM(II) CHARGE-TRANSFER SENSITIZERS (X = CL-, BR-, I-, CN-, AND SCN-) ON NANOCRYSTALLINE TIO2 ELECTRODES [J].
NAZEERUDDIN, MK ;
KAY, A ;
RODICIO, I ;
HUMPHRYBAKER, R ;
MULLER, E ;
LISKA, P ;
VLACHOPOULOS, N ;
GRATZEL, M .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (14) :6382-6390
[23]   Heteroepitaxial electrodeposition of zinc oxide films on gallium nitride [J].
Pauporté, T ;
Lincot, D .
APPLIED PHYSICS LETTERS, 1999, 75 (24) :3817-3819
[24]   Reaction of NO2 with Zn and ZnO:: Photoemission, XANES, and density functional studies on the formation of NO3 [J].
Rodriguez, JA ;
Jirsak, T ;
Dvorak, J ;
Sambasivan, S ;
Fischer, D .
JOURNAL OF PHYSICAL CHEMISTRY B, 2000, 104 (02) :319-328
[25]   GIANT-OSCILLATOR-STRENGTH EFFECT ON EXCITONIC OPTICAL NONLINEARITIES DUE TO LOCALIZATION [J].
TAKAGAHARA, T ;
HANAMURA, E .
PHYSICAL REVIEW LETTERS, 1986, 56 (23) :2533-2536
[26]   Room-temperature ultraviolet laser emission from self-assembled ZnO microcrystallite thin films [J].
Tang, ZK ;
Wong, GKL ;
Yu, P ;
Kawasaki, M ;
Ohtomo, A ;
Koinuma, H ;
Segawa, Y .
APPLIED PHYSICS LETTERS, 1998, 72 (25) :3270-3272
[27]   Mechanisms behind green photoluminescence in ZnO phosphor powders [J].
Vanheusden, K ;
Warren, WL ;
Seager, CH ;
Tallant, DR ;
Voigt, JA ;
Gnade, BE .
JOURNAL OF APPLIED PHYSICS, 1996, 79 (10) :7983-7990
[28]   Induced growth of asymmetric nanocantilever arrays on polar surfaces [J].
Wang, ZL ;
Kong, XY ;
Zuo, JM .
PHYSICAL REVIEW LETTERS, 2003, 91 (18) :185502-185502
[29]   Electrochemical growth of ZnO nano-rods on polycrystalline Zn foil [J].
Wong, MH ;
Berenov, A ;
Qi, X ;
Kappers, MJ ;
Barber, ZH ;
Illy, B ;
Lockman, Z ;
Ryan, MP ;
MacManus-Driscoll, JL .
NANOTECHNOLOGY, 2003, 14 (09) :968-973
[30]   Zinc oxide nanodisk [J].
Xu, CX ;
Sun, XW ;
Dong, ZL ;
Yu, MB .
APPLIED PHYSICS LETTERS, 2004, 85 (17) :3878-3880