Ring-Opening/Expansion Rearrangement of Cycloprop[2,3]inden-1-ols Catalyzed by p-Toluenesulfonic Acid

被引：5
作者：
Li, Pei-Fang [1 ,2 ]
Yi, Cheng-Bo [1 ,2 ]
Ren, Shu-Jian [1 ,2 ]
Qu, Jin [1 ,2 ]
机构：
[1] Nankai Univ, Key Lab, Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Res Inst Elementoorgan Chem, Tianjin 300071, Peoples R China
[2] Nankai Univ, Inst Elementoorgan Chem, Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Res Inst Elementoorgan Chem, Tianjin 300071, Peoples R China
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2016年 / 358卷 / 13期
基金：
中国国家自然科学基金;
关键词：
benzofulvenes; naphthalenes; rearrangement; ring-expansion; ring-opening; NAZAROV-TYPE CYCLIZATIONS; BRONSTED ACID; SUBSTITUTED NAPHTHALENES; LEWIS-ACID; HOT-WATER; BENZOFULVENE DERIVATIVES; SULINDAC DERIVATIVES; INTERNAL ALKYNES; STACKED POLYMER; CONSTRUCTION;
D O I：
10.1002/adsc.201600246
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
A divergent approach to generate either 1-hydroxymethylindenes (which could then be converted to benzofulvenes through a dehydration reaction) or naphthalenes by the rearrangement of cycloprop[2,3]inden-1-ols is reported. The effect of the cyclopropyl ring substitution pattern on ring-opening/expansion rearrangements of the substrates was systemically studied.
引用
收藏
页码：2088 / 2092
页数：5
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