Sewage Sludge Torrefaction in an Auger Reactor

被引:43
作者
Atienza-Martinez, Maria [1 ]
Francisco Mastral, Jose [1 ]
Abrego, Javier [1 ]
Ceamanos, Jesus [1 ]
Gea, Gloria [1 ]
机构
[1] Univ Zaragoza, GPT, Aragon Inst Engn Res I3A, Zaragoza 50018, Spain
关键词
FAST-PYROLYSIS; FLUIDIZED-BED; OPERATIONAL CONDITIONS; THERMOCHEMICAL TREATMENT; MICROWAVE PYROLYSIS; GAS-CHROMATOGRAPHY; BIOMASS; CRACKING; SAWDUST; ENERGY;
D O I
10.1021/ef501425h
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
A lab-scale auger reactor was used for the study of dry sewage sludge torrefaction. The influence of the torrefaction temperature (between 250 and 300 degrees C) and the solid residence time (between 13 and 35 min) on the product distribution and properties was investigated. The results have shown that both parameters affect dry sewage sludge torrefaction products to a similar extent within the ranges of study. The yield of torrefied sewage sludge decreases when increasing the torrefaction temperature and the solid residence time, while the yields of liquid and noncondensable gases show the opposite trend. Carbon dioxide and hydrogen sulfide are the major noncondensable products. The yield of water is higher than the initial moisture content of sewage sludge. Organic compounds are also released during torrefaction, especially under severe conditions. Torrefaction liquid separates into an organic phase and an aqueous phase. The former is rich in oxygen-containing aliphatic compounds and steroids and their derivatives. The latter is rich in oxygen-containing aliphatic compounds and oxygen- and nitrogen-containing aliphatic compounds. Torrefaction pretreatment eases sewage sludge grindability and improves some of its fuel properties. O/C and H/C molar ratios of the torrefied solid are lower than those of the dry sewage sludge, while the higher heating value (daf) is higher. The energy density is higher under specific torrefaction conditions.
引用
收藏
页码:160 / 170
页数:11
相关论文
共 46 条
[1]   Technical and Energetic Assessment of a Three-Stage Thermochemical Treatment for Sewage Sludge [J].
Abrego, Javier ;
Luis Sanchez, Jose ;
Arauzo, Jesus ;
Fonts, Isabel ;
Gil-Lalaguna, Noemi ;
Atienza-Martinez, Maria .
ENERGY & FUELS, 2013, 27 (02) :1026-1034
[2]  
[Anonymous], J ANAL APPL PYROLYSI
[3]  
[Anonymous], 2013, BIOMASS GASIFICATION
[4]   Influence of torrefaction on the grindability and reactivity of woody biomass [J].
Arias, B. ;
Pevida, C. ;
Fermoso, J. ;
Plaza, M. G. ;
Rubiera, F. ;
Pis, J. J. .
FUEL PROCESSING TECHNOLOGY, 2008, 89 (02) :169-175
[5]   Thermal deoxygenation and pyrolysis of oleic acid [J].
Asomaning, Justice ;
Mussone, Paolo ;
Bressler, David C. .
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2014, 105 :1-7
[6]   Fast pyrolysis of torrefied sewage sludge in a fluidized bed reactor [J].
Atienza-Martinez, M. ;
Fonts, I. ;
Lazaro, L. ;
Ceamanos, J. ;
Gea, G. .
CHEMICAL ENGINEERING JOURNAL, 2015, 259 :467-480
[7]   Sewage sludge torrefaction in a fluidized bed reactor [J].
Atienza-Martinez, M. ;
Fonts, I. ;
Abrego, J. ;
Ceamanos, J. ;
Gea, G. .
CHEMICAL ENGINEERING JOURNAL, 2013, 222 :534-545
[8]   Fast pyrolysis of biomass thermally pretreated by torrefaction [J].
Boateng, A. A. ;
Mullen, C. A. .
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2013, 100 :95-102
[9]   FUELS AND CHEMICALS FROM SEWAGE-SLUDGE .2. THE PRODUCTION OF ALKANES AND ALKENES BY THE PYROLYSIS OF TRIGLYCERIDES OVER ACTIVATED ALUMINA [J].
BOOCOCK, DGB ;
KONAR, SK ;
MACKAY, A ;
CHEUNG, PTC ;
LIU, J .
FUEL, 1992, 71 (11) :1291-1297
[10]   Characterization of Products from Torrefaction of Sprucewood and Bagasse in an Auger Reactor [J].
Chang, Sheng ;
Zhao, Zengli ;
Zheng, Anqing ;
He, Fang ;
Huang, Zhen ;
Li, Haibin .
ENERGY & FUELS, 2012, 26 (11) :7009-7017