Synthesis and Characterization of Metal Complexes of a New Unsymmetrical Tridentate NNS Schiff Base Ligand: X-ray Crystal Structure Determination of Nickel(II) Complex

被引：2
|
作者：
Dehghani-Firouzabadi, Ahmad Ali [1 ]
Sepehri, Samaneh [1 ]
Notash, Behrouz [2 ]
机构：
[1] Yazd Univ, Dept Chem, Fac Sci, Yazd 89195741, Iran
[2] Shahid Beheshti Univ, Dept Chem, GC Evin, Tehran 1983963113, Iran
来源：
JOURNAL OF THE CHINESE CHEMICAL SOCIETY | 2017年 / 64卷 / 09期
关键词：
NNS donor; Tridentate ligand; Unsymmetrical ligand; Schiff base complexes; Thioether ligand; Ni(II) complex; COPPER(II) COMPLEXES; ZINC-COMPLEXES; DONOR LIGAND; N; S LIGAND; COORDINATION; CU(II); THIOETHER; NI(II); NITROGEN; SULFUR;
D O I：
10.1002/jccs.201700068
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new unsymmetrical tridentate NNS Schiff base ligand, 2-(2-nitrophenylthio)-N-((pyridine-2-yl)methylene)benzenamine (L), and its Mn(II), Ni(II), Cu(II), and Zn(II) complexes were synthesized. These compounds were characterized by different physicochemical and spectroscopic techniques. The molecular structure of [NiL2 ](ClO4 )(2) was determined by single-crystal X-ray diffraction. In this complex, two ligands coordinate through azomethine-N, pyridine-N, and thioether-S, forming a mononuclear 6-coordinate distorted octahedral geometry about a nickel.
引用
收藏
页码：1104 / 1110
页数：7
相关论文
共 50 条
12345