Electron Transfer Reactions in Atom Transfer Radical Polymerization

被引：33

作者：

Fantin, Marco ^{[1
]}

Lorandi, Francesca ^{[2
]}

Gennaro, Armando ^{[2
]}

Isse, Abdirisak A. ^{[2
]}

Matyjaszewski, Krzysztof ^{[1
]}

机构：

[1] Carnegie Mellon Univ, Dept Chem, 4400 5th Ave, Pittsburgh, PA 15213 USA

[2] Univ Padua, Dept Chem Sci, Via Marzolo 1, I-35131 Padua, Italy

来源：

SYNTHESIS-STUTTGART | 2017年 / 49卷 / 15期

关键词：

atom transfer reactions; electrochemical properties; metal catalyzed atom abstraction; alkyl halides; alkyl radicals; eATRP; ATRA; COPPER-COMPLEXES; THERMODYNAMIC PROPERTIES; SARA ATRP; CATALYST; MINIEMULSION; INITIATOR; HALIDES; RDRP; CU-0; ACTIVATION;

D O I：

10.1055/s-0036-1588873

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Electrochemistry may seem an outsider to the field of polymer science and controlled radical polymerization. Nevertheless, several electrochemical methods have been used to determine the mechanism of atom transfer radical polymerization (ATRP), using both a thermodynamic and a kinetic approach. Indeed, electron transfer reactions involving the metal catalyst, initiator/dormant species, and propagating radicals play a crucial role in ATRP. In this mini-review, electrochemical properties of ATRP catalysts and initiators are discussed, together with the mechanism of the atom and electron transfer in ATRP.

引用

页码：3311 / 3322

页数：12

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