Chemoselective reduction of α,β-unsaturated aldehydes using an unsupported nanoporous gold catalyst

被引：40
作者：
Takale, Balaram S. [1 ]
Wang, Shanqiang [1 ]
Zhang, Xuan [2 ]
Feng, Xiujuan [1 ]
Yu, Xiaoqiang [1 ]
Jin, Tienan [2 ]
Bao, Ming [1 ]
Yamamoto, Yoshinori [1 ,2 ]
机构：
[1] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116023, Peoples R China
[2] Tohoku Univ, WPI Adv Inst Mat Res, Sendai, Miyagi 9808577, Japan
来源：
CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 92期
关键词：
SELECTIVE HYDROGENATION; CARBONYL-COMPOUNDS; LIQUID-PHASE; NANOSTRUCTURED MATERIALS; AEROBIC OXIDATION; ALKYNES; ALCOHOLS; HYDROSILYLATION; NANOPARTICLES; COEXISTENCE;
D O I：
10.1039/c4cc07068b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The remarkable effect of an unsupported nanoporous gold catalyst (AuNPore) on chemoselective hydrogenation of alpha,beta-unsaturated aldehydes using silane has been described. Enals can be reduced with excellent selectivity, giving the corresponding allylic alcohols in good to high chemical yields.
引用
收藏
页码：14401 / 14404
页数：4
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