Chemoselective reduction of α,β-unsaturated aldehydes using an unsupported nanoporous gold catalyst

被引：40

作者：

Takale, Balaram S. ^{[1
]}

Wang, Shanqiang ^{[1
]}

Zhang, Xuan ^{[2
]}

Feng, Xiujuan ^{[1
]}

Yu, Xiaoqiang ^{[1
]}

Jin, Tienan ^{[2
]}

Bao, Ming ^{[1
]}

Yamamoto, Yoshinori ^{[1
,2
]}

机构：

[1] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116023, Peoples R China

[2] Tohoku Univ, WPI Adv Inst Mat Res, Sendai, Miyagi 9808577, Japan

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 92期

关键词：

SELECTIVE HYDROGENATION; CARBONYL-COMPOUNDS; LIQUID-PHASE; NANOSTRUCTURED MATERIALS; AEROBIC OXIDATION; ALKYNES; ALCOHOLS; HYDROSILYLATION; NANOPARTICLES; COEXISTENCE;

D O I：

10.1039/c4cc07068b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The remarkable effect of an unsupported nanoporous gold catalyst (AuNPore) on chemoselective hydrogenation of alpha,beta-unsaturated aldehydes using silane has been described. Enals can be reduced with excellent selectivity, giving the corresponding allylic alcohols in good to high chemical yields.

引用

页码：14401 / 14404

页数：4

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