Crosslinking polymerization of polyfunctional monomers by free radical mechanism

被引：0
作者：
Vlad, Cristina Doina [1 ]
Vasiliu, Silvia [1 ]
机构：
[1] Petru Poni Inst Macromol Chem, Iasi 700487, Romania
来源：
POLIMERY | 2010年 / 55卷 / 03期
关键词：
crosslinking; radical polymerization; suspension polymerization; diallyl maleate; methyl methacrylate; copolymer; diluent; porosity; ION-EXCHANGE-RESINS; COPOLYMERIZATION; POLYMERS; BEADS;
D O I：
暂无
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The crosslinked architectures based on diallyl maleate (DAM) obtained by suspension polymerization techniques have been studied. The influence of synthesis parameters on the structure of poly(diallyl maleate) [poly(DAM)] and copolymers of DAM with methyl methacrylate (MM) [poly(DAM-co-MM)] was also investigated. The effect of the diluents (n-butyl acetate or cyclohexanole) on the inner macroporous structure (apparent and skeletal density, pore volume, total porosity, cyclohexane uptake) has been studied. The experimental results showed that the values of the solvent uptake are strongly influenced by the diluent quantity as well as its solubility parameter.
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页码：181 / 185
页数：5
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