Insertion of a N-heterocyclic carbene (NHC) into a platinum-olefin bond

被引：42
|
作者：
Fantasia, Serena
Jacobsen, Heiko
Cavallo, Luigi
Nolan, Steven P.
机构：
[1] Inst Chem Res Catalonia ICIQ, Tarragona 43007, Spain
[2] KemKom, D-25917 Leck, Germany
[3] Univ Salerno, Dipartimento Chim, I-84081 Baronissi, SA, Italy
来源：
ORGANOMETALLICS | 2007年 / 26卷 / 14期
关键词：
D O I：
10.1021/om700447u
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The insertion of a N-heterocyclic carbene (NHC) into a coordinated olefin moiety is observed for a Pt-based system. Important intermediates along the reaction pathway have been isolated and fully characterized. Computational work supports a proposed mechanistic pathway involving external attack at the olefin by a NHC ligand rather than an intramolecular migratory insertion route.
引用
收藏
页码：3286 / 3288
页数：3
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