Visible-light-induced three-component reaction of quinoxalin-2(1H)-ones, alkenes and CF3SO2Na leading to 3-trifluoroalkylated quinoxalin-2(1H)-ones

被引：148

作者：

Meng, Na ^{[1
]}

Lv, Yufen ^{[1
]}

Liu, Qishun ^{[1
]}

Liu, Ruisheng ^{[1
]}

Zhao, Xiaohui ^{[2
,3
]}

Wei, Wei ^{[1
,2
,3
]}

机构：

[1] Qufu Normal Univ, Sch Chem & Chem Engn, Qufu 273165, Shandong, Peoples R China

[2] Chinese Acad Sci, Northwest Inst Plateau Biol, Qinghai Prov Key Lab Tibetan Med Res, Xining 810008, Qinghai, Peoples R China

[3] Chinese Acad Sci, Northwest Inst Plateau Biol, Key Lab Tibetan Med Res, Xining 810008, Qinghai, Peoples R China

来源：

CHINESE CHEMICAL LETTERS | 2021年 / 32卷 / 01期

关键词：

Metal-free; Visible-light-catalysis; Three-component reaction; Quinoxalin-2(1H)-ones; INDUCED DEOXYGENATIVE C2-SULFONYLATION; C-H TRIFLUOROMETHYLATION; QUINOLINE N-OXIDES; METAL; DESIGN; QUINOXALIN-2(H)-ONES; ARYLATION; ANTITUMOR; FLUORINE; OXIDANT;

D O I：

10.1016/j.cclet.2020.11.034

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A facile and metal-free visible-light-enabled three-component reaction of quinoxalin-2(1H)-ones, alkenes and CF3SO2Na has been developed under air at room temperature. This photocatalytic tandem reaction using 4CzIPN as the photocatalyst and air as the green oxidant, provides a mild and environmentally friendly approach to access a series of 3-trifluoroalkylated quinoxalin-2(1H)-ones. (C) 2020 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.

引用

页码：258 / 262

页数：5

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