Visible-light-induced three-component reaction of quinoxalin-2(1H)-ones, alkenes and CF3SO2Na leading to 3-trifluoroalkylated quinoxalin-2(1H)-ones

被引：148
作者：
Meng, Na [1 ]
Lv, Yufen [1 ]
Liu, Qishun [1 ]
Liu, Ruisheng [1 ]
Zhao, Xiaohui [2 ,3 ]
Wei, Wei [1 ,2 ,3 ]
机构：
[1] Qufu Normal Univ, Sch Chem & Chem Engn, Qufu 273165, Shandong, Peoples R China
[2] Chinese Acad Sci, Northwest Inst Plateau Biol, Qinghai Prov Key Lab Tibetan Med Res, Xining 810008, Qinghai, Peoples R China
[3] Chinese Acad Sci, Northwest Inst Plateau Biol, Key Lab Tibetan Med Res, Xining 810008, Qinghai, Peoples R China
来源：
CHINESE CHEMICAL LETTERS | 2021年 / 32卷 / 01期
关键词：
Metal-free; Visible-light-catalysis; Three-component reaction; Quinoxalin-2(1H)-ones; INDUCED DEOXYGENATIVE C2-SULFONYLATION; C-H TRIFLUOROMETHYLATION; QUINOLINE N-OXIDES; METAL; DESIGN; QUINOXALIN-2(H)-ONES; ARYLATION; ANTITUMOR; FLUORINE; OXIDANT;
D O I：
10.1016/j.cclet.2020.11.034
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A facile and metal-free visible-light-enabled three-component reaction of quinoxalin-2(1H)-ones, alkenes and CF3SO2Na has been developed under air at room temperature. This photocatalytic tandem reaction using 4CzIPN as the photocatalyst and air as the green oxidant, provides a mild and environmentally friendly approach to access a series of 3-trifluoroalkylated quinoxalin-2(1H)-ones. (C) 2020 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码：258 / 262
页数：5
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