Absolute configuration of a ceramide with a novel branched-chain fatty acid isolated from the epiphytic dinoflagellate, Coolia monotis

被引：20
作者：
Akasaka, K
Shichijyukari, S
Matsuoka, S
Murata, M
Meguro, H
Ohrui, H
机构：
[1] Tohoku Univ, Grad Sch Agr Sci, Aoba Ku, Sendai, Miyagi 9818555, Japan
[2] Osaka Univ, Grad Sch Sci, Toyonaka, Osaka 5600043, Japan
[3] Tohoku Fukushi Univ, Aoba Ku, Sendai, Miyagi 9810943, Japan
来源：
BIOSCIENCE BIOTECHNOLOGY AND BIOCHEMISTRY | 2000年 / 64卷 / 09期
关键词：
absolute configuration; chiral discrimination; branched-chain fatty acid; chiral conversion reagent;
D O I：
10.1271/bbb.64.1842
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
The absolute configuration of the chiral center at the C15 position of a novel branched-chain fatty acid derived from a new ceramide isolated from the epiphytic dinoflagellate Coolia monotis was determined to be of R from by reversed-phase HPLC after cleavage to 12-methylpentadecanoic acid and subsequent conversion with the chiral fluorescent reagent, (1R,2R)-2-(2,3-anthracenedicarboximido)cyclohexanol.
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收藏
页码：1842 / 1846
页数：5
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