Supramolecular Polymer of Near-Infrared Luminescent Porphyrin Glass

被引：16

作者：

Morisue, Mitsuhiko ^{[1
]}

Hoshino, Yuki ^{[1
]}

Shimizu, Masaki ^{[1
]}

Nakanishi, Takayuki ^{[3
]}

Hasegawa, Yasuchika ^{[3
]}

Hossain, Md Amran ^{[2
]}

Sakurai, Shinichi ^{[2
]}

Sasaki, Sono ^{[2
]}

Uemura, Shinobu ^{[4
]}

Matsui, Jun ^{[5
]}

机构：

[1] Kyoto Inst Technol, Fac Mol Chem & Engn, Sakyo Ku, Kyoto 6068585, Japan

[2] Kyoto Inst Technol, Fac Fiber Sci & Engn, Sakyo Ku, Kyoto 6068585, Japan

[3] Hokkaido Univ, Grad Sch Engn, Kita Ku, North 13 West 8, Sapporo, Hokkaido 0608628, Japan

[4] Kagawa Univ, Dept Adv Mat Sci, Hayashi Cho, Takamatsu, Kagawa 7610396, Japan

[5] Yamagata Univ, Fac Sci, Dept Mat & Biol Chem, Kojirakawa Cho, Yamagata 9908560, Japan

来源：

MACROMOLECULES | 2017年 / 50卷 / 08期

关键词：

ORGANIC SEMICONDUCTORS; CONJUGATED POLYMER; CRYSTAL-STRUCTURE; CHARGE-TRANSPORT; OLIGOMERS; COMPLEX; SPECTROSCOPY; MOLECULES; BACTERIA; DESIGN;

D O I：

10.1021/acs.macromol.7b00316

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A comprehensive study of supramolecular polymerization of ditopic zinc (2-pyridylethynyl)porphyrin dimer 1 in toluene and thin films was performed. A glass-forming porphyrin bearing 3,4,5-tri((S)-3,7-dimethyloctyloxy)phenyl groups, named "porphyrin glass", was introduced with the 2-pyridylethynyl group as a supramolecular organizing unit; two zinc (2-pyridylethynyl)porphyrins were held together by self-complementary pyridyl-tozinc coordination bonds to form a slipped-cofacial stack. Then, ditopic zinc (2-pyridylethynyl)porphyrin could be extended to a linear supramolecular polymer. The small binding constant limited the degree of supramolecular polymerization of 1 in toluene solution. In spin-cast film, on the other hand, 1 adopted a form of supramolecular polymer of porphyrin glass, which was effective enough to display a large bathochromic shift of the absorption bands exceeding the narrowest limit of the optical band gap extrapolated from the electronic structures in solution. The supramolecularly polymerized porphyrin glass formed excimer,which exhibited solid-state near-infrared (NIR) luminescence at approximately 1025 nm.

引用

页码：3186 / 3192

页数：7