An Electrochemical Study of Sb/Acetylene Black Composite as Anode for Sodium-Ion Batteries

被引：78
作者：
Hou, Hongshuai [1 ]
Yang, Yingchang [1 ]
Zhu, Yirong [1 ]
Jing, Mingjun [1 ]
Pan, Chengchi [1 ]
Fang, Laibing [1 ]
Song, Weixin [1 ]
Yang, Xuming [1 ]
Ji, Xiaobo [1 ]
机构：
[1] Cent S Univ, Coll Chem & Chem Engn, Changsha 410083, Hunan, Peoples R China
来源：
ELECTROCHIMICA ACTA | 2014年 / 146卷
基金：
中国国家自然科学基金;
关键词：
Sb; acetylene black; composite; sodium-ion battery; anode; SUPERIOR RATE CAPABILITY; HIGH-PERFORMANCE; HIGH-CAPACITY; LOW-COST; NA-STORAGE; LI-ION; CARBON; CATHODE; SB; NANOCOMPOSITES;
D O I：
10.1016/j.electacta.2014.09.080
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
Sb/acetylene black (Sb/AB) composite was firstly applied as anode for sodium-ion batteries (SIBs). A great electrochemical performance of the composite was obtained when utilizing this composite for SIBs. It was found that the charge capacity can reach 473 mAhg(-1) in the 70th cycle at a current density of 100mA g(-1), and we also note that the capacity contributed by Sb was about 624 mAhg(-1), which is very close to its theoretical sodium storage capacity (660 mAhg(-1) corresponding to a formula of Na3Sb), demonstrating the full utilization of Sb. It is interesting to see that even at a high current density of 1600 mAg(-1), the capacity can still reach 281 mAhg(-1). (C) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码：328 / 334
页数：7
相关论文
共 46 条
[21]   Spherical Carbon as a New High-Rate Anode for Sodium-ion Batteries [J].
Pol, Vilas G. ;
Lee, Eungje ;
Zhou, Dehua ;
Dogan, Fulya ;
Calderon-Moreno, Jose M. ;
Johnson, Christopher S. .
ELECTROCHIMICA ACTA, 2014, 127 :61-67
[22]   High capacity hard carbon anodes for sodium ion batteries in additive free electrolyte [J].
Ponrouch, A. ;
Goni, A. R. ;
Rosa Palacin, M. .
ELECTROCHEMISTRY COMMUNICATIONS, 2013, 27 :85-88
[23]   High Capacity and Rate Capability of Amorphous Phosphorus for Sodium Ion Batteries [J].
Qian, Jiangfeng ;
Wu, Xianyong ;
Cao, Yuliang ;
Ai, Xinping ;
Yang, Hanxi .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (17) :4633-4636
[24]   High capacity Na-storage and superior cyclability of nanocomposite Sb/C anode for Na-ion batteries [J].
Qian, Jiangfeng ;
Chen, Yao ;
Wu, Lin ;
Cao, Yuliang ;
Ai, Xinping ;
Yang, Hanxi .
CHEMICAL COMMUNICATIONS, 2012, 48 (56) :7070-7072
[25]   Graphene Networks Anchored with Sn@Graphene as Lithium Ion Battery Anode [J].
Qin, Jian ;
He, Chunnian ;
Zhao, Naiqin ;
Wang, Zhiyuan ;
Shi, Chunsheng ;
Liu, En-Zuo ;
Li, Jiajun .
ACS NANO, 2014, 8 (02) :1728-1738
[26]   Na2Ti3O7: an intercalation based anode for sodium-ion battery applications [J].
Rudola, Ashish ;
Saravanan, Kuppan ;
Mason, Chad W. ;
Balaya, Palani .
JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (07) :2653-2662
[27]   The First Report on Excellent Cycling Stability and Superior Rate Capability of Na3V2(PO4)3 for Sodium Ion Batteries [J].
Saravanan, Kuppan ;
Mason, Chad W. ;
Rudola, Ashish ;
Wong, Kim Hai ;
Balaya, Palani .
ADVANCED ENERGY MATERIALS, 2013, 3 (04) :444-450
[28]   New materials based on a layered sodium titanate for dual electrochemical Na and Li intercalation systems [J].
Shirpour, Mona ;
Cabana, Jordi ;
Doeff, Marca .
ENERGY & ENVIRONMENTAL SCIENCE, 2013, 6 (08) :2538-2547
[29]   Sodium-Ion Batteries [J].
Slater, Michael D. ;
Kim, Donghan ;
Lee, Eungje ;
Johnson, Christopher S. .
ADVANCED FUNCTIONAL MATERIALS, 2013, 23 (08) :947-958
[30]   SnO2@graphene nanocomposites as anode materials for Na-ion batteries with superior electrochemical performance [J].
Su, Dawei ;
Ahn, Hyo-Jun ;
Wang, Guoxiu .
CHEMICAL COMMUNICATIONS, 2013, 49 (30) :3131-3133
12345