An Electrochemical Study of Sb/Acetylene Black Composite as Anode for Sodium-Ion Batteries

被引：79
作者：
Hou, Hongshuai [1 ]
Yang, Yingchang [1 ]
Zhu, Yirong [1 ]
Jing, Mingjun [1 ]
Pan, Chengchi [1 ]
Fang, Laibing [1 ]
Song, Weixin [1 ]
Yang, Xuming [1 ]
Ji, Xiaobo [1 ]
机构：
[1] Cent S Univ, Coll Chem & Chem Engn, Changsha 410083, Hunan, Peoples R China
来源：
ELECTROCHIMICA ACTA | 2014年 / 146卷
基金：
中国国家自然科学基金;
关键词：
Sb; acetylene black; composite; sodium-ion battery; anode; SUPERIOR RATE CAPABILITY; HIGH-PERFORMANCE; HIGH-CAPACITY; LOW-COST; NA-STORAGE; LI-ION; CARBON; CATHODE; SB; NANOCOMPOSITES;
D O I：
10.1016/j.electacta.2014.09.080
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
Sb/acetylene black (Sb/AB) composite was firstly applied as anode for sodium-ion batteries (SIBs). A great electrochemical performance of the composite was obtained when utilizing this composite for SIBs. It was found that the charge capacity can reach 473 mAhg(-1) in the 70th cycle at a current density of 100mA g(-1), and we also note that the capacity contributed by Sb was about 624 mAhg(-1), which is very close to its theoretical sodium storage capacity (660 mAhg(-1) corresponding to a formula of Na3Sb), demonstrating the full utilization of Sb. It is interesting to see that even at a high current density of 1600 mAg(-1), the capacity can still reach 281 mAhg(-1). (C) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码：328 / 334
页数：7
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