An Electrochemical Study of Sb/Acetylene Black Composite as Anode for Sodium-Ion Batteries

被引：78

作者：

Hou, Hongshuai ^{[1
]}

Yang, Yingchang ^{[1
]}

Zhu, Yirong ^{[1
]}

Jing, Mingjun ^{[1
]}

Pan, Chengchi ^{[1
]}

Fang, Laibing ^{[1
]}

Song, Weixin ^{[1
]}

Yang, Xuming ^{[1
]}

Ji, Xiaobo ^{[1
]}

机构：

[1] Cent S Univ, Coll Chem & Chem Engn, Changsha 410083, Hunan, Peoples R China

来源：

ELECTROCHIMICA ACTA | 2014年 / 146卷

基金：

中国国家自然科学基金;

关键词：

Sb; acetylene black; composite; sodium-ion battery; anode; SUPERIOR RATE CAPABILITY; HIGH-PERFORMANCE; HIGH-CAPACITY; LOW-COST; NA-STORAGE; LI-ION; CARBON; CATHODE; SB; NANOCOMPOSITES;

D O I：

10.1016/j.electacta.2014.09.080

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Sb/acetylene black (Sb/AB) composite was firstly applied as anode for sodium-ion batteries (SIBs). A great electrochemical performance of the composite was obtained when utilizing this composite for SIBs. It was found that the charge capacity can reach 473 mAhg(-1) in the 70th cycle at a current density of 100mA g(-1), and we also note that the capacity contributed by Sb was about 624 mAhg(-1), which is very close to its theoretical sodium storage capacity (660 mAhg(-1) corresponding to a formula of Na3Sb), demonstrating the full utilization of Sb. It is interesting to see that even at a high current density of 1600 mAg(-1), the capacity can still reach 281 mAhg(-1). (C) 2014 Elsevier Ltd. All rights reserved.

引用

页码：328 / 334

页数：7

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