Suzuki-Miyaura Cross-Coupling Reactions in Aqueous Media: Green and Sustainable Syntheses of Biaryls

被引：340
作者：
Polshettiwar, Vivek [1 ]
Decottignies, Audrey [2 ]
Len, Christophe [2 ]
Fihri, Aziz [2 ]
机构：
[1] King Abdullah Univ Sci & Technol, KCC, Thuwal 23955, Saudi Arabia
[2] ESCOM UTC, F-60200 Compiegne, France
来源：
CHEMSUSCHEM | 2010年 / 3卷 / 05期
关键词：
cross coupling; green chemistry; microwave chemistry; palladium; sustainable chemistry; water chemistry; RING-CLOSING METATHESIS; ARYL CHLORIDES; ROOM-TEMPERATURE; ARYLBORONIC ACIDS; PALLADIUM-COMPLEX; PHENYLBORONIC ACID; AEROBIC CONDITIONS; MESOPOROUS SILICA; UNPROTECTED HALONUCLEOSIDES; CARBAPALLADACYCLE COMPLEX;
D O I：
10.1002/cssc.200900221
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Carbon-carbon cross-coupling reactions are among the most important processes in organic chemistry, and Suzuki-Miyaura reactions are among the most widely used protocols for the formation of carbon-carbon bonds. These reactions are generally catalyzed by soluble palladium complexes with various ligands. However, the use of toxic organic solvents remains a scientific Challenge and an aspect of economical and ecological relevance. This-Review will summarize various recently developed significant methods by which the Suzuki-Miyaura coupling was conducted in aqueous media, and analyzes if they are "real green" protocols.
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页码：502 / 522
页数：21
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