Formation of CMK-3/Co3O4 nanosheets on nickel foam with markedly enhanced pseudocapacitive properties

被引:23
作者
Zhang, Guoxing [1 ]
Chen, Yuemei [1 ]
Jiang, Yingjian [1 ]
Lin, Chuan [2 ]
Chen, Yigang [1 ]
Guo, Haibo [1 ]
机构
[1] Shanghai Univ, Sch Mat Sci & Engn, Dept Elect Informat Mat, Shanghai 200444, Peoples R China
[2] GE Global Res, China Technol Ctr, Shanghai 201203, Peoples R China
关键词
CMK-3; Nanosheet; Cobalt oxide; Energy storage; Supercapacitor; HIGH-PERFORMANCE SUPERCAPACITORS; ELECTROCHEMICAL ENERGY-STORAGE; ORDERED MESOPOROUS CARBON; CO3O4; CAPACITORS; NANOWIRES; NANOCOMPOSITE; COMPOSITES; ELECTRODEPOSITION; NANOSTRUCTURES;
D O I
10.1016/j.jmst.2017.12.018
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Composites of mesoporous carbon (CMK-3) and Co3O4 nanosheets grown on nickel foam were successfully synthesized by a simple route. A bare Co3O4 film was synthesized for comparison. With the addition of CMK-3, the Co3O4 nanoparticles self-organize and agglomerate into nanosheets, showing a significant influence by CMK-3 on the morphology. The CMK-3/Co3O4 exhibits an optimal specific capacitance of 1131.3 F g(-1) in 3 mol L-1 KOH aqueous electrolyte at 0.5 A g(-1), and a retention ratio of 91% over 3000 cycles, both being much higher than that achieved from the bare Co3O4 film (727 F g(-1) of specific capacitance, and 82% capacitance retention ratio), indicating that the CMK-3/Co3O4 nanosheets are very promising as electrode materials for supercapacitor applications. (C) 2018 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.
引用
收藏
页码:1538 / 1543
页数:6
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