Oxidation catalysis of a manganese(III)porphyrin intercalated in layered double hydroxide clays

被引：46

作者：

Tong, ZW

Shichi, T

Takagi, K ^{[1
]}

机构：

[1] Nagoya Univ, Dept Crystalline Mat Sci, Grad Sch Engn, Chikusa Ku, Nagoya, Aichi 4648603, Japan

[2] JST, CREST, Tokyo, Japan

来源：

MATERIALS LETTERS | 2003年 / 57卷 / 15期

关键词：

layered double hydroxide; tetra(p-ulfonatophenyl)porphinatomanganese(III) anion; intercalation; catalysts; nanocomposites;

D O I：

10.1016/S0167-577X(02)01206-5

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Tetra(p-sulfonatophenyl)porphinatomanganese(III) anions, [Mn(III)TSPPCl](4-) were intercalated into the interlayer spaces of Mg-Al-layered double hydroxide (LDH) and studied as a catalyst for the oxidation of 2,4,6-trichlorophenol (TCP). The Mn(III)TSPP anions could be efficiently intercalated into the LDH interlayers as a perpendicular Mn(III)TSPP/LDH complex by adsorbing the guest molecules, which is a characteristic for easy handling and a high catalytic activity. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：2258 / 2261

页数：4

共 14 条

[1]

BARLOY L, 1992, NEW J CHEM, V16, P71

[2]

CARRADO KA, 1993, CHEM MATER, V5, P427

[3] INTERCALATION OF ORGANIC AND INORGANIC ANIONS INTO LAYERED DOUBLE HYDROXIDES [J].