A new synthetic route to heteroarylsilanes via ruthenium-catalyzed C-H/SiR3 coupling

被引：64

作者：

Kakiuchi, F

Matsumoto, M

Sonoda, M

Fukuyama, T

Chatani, N

Murai, S

Furukawa, N

Seki, Y

机构：

[1] Osaka Univ, Fac Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan

[2] Kagawa Univ, Fac Econ, Lab Commod Sci, Takamatsu, Kagawa 7608523, Japan

来源：

CHEMISTRY LETTERS | 2000年 / 07期

关键词：

D O I：

10.1246/cl.2000.750

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Heteroarylsilanes can be synthesized by the reaction of heteroaromatic compounds with triorganovinylsilanes with the aid of a Ru-3(CO)(12)-catalyst. A variety of heteroaromatic compounds can be used in this C-H/SiR3 coupling. The coupling reaction was observed to take place at a position beta to the directing carbonyl group, e.g., ketone, ester, and amide, in the case of heteroaromatic compounds.

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页码：750 / 751

页数：2

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