Effects of magnetite on magnetic coating behavior in pentlandite and serpentine system

被引:42
作者
Lu, Jiwei [1 ]
Yuan, Zhitao [1 ]
Liu, Jiongtian [1 ,2 ]
Li, Lixia [1 ]
Zhu, Shuo [1 ]
机构
[1] Northeastern Univ, Sch Resources & Civil Engn, Shenyang 110819, Peoples R China
[2] Zhengzhou Univ, Sch Chem & Energy, Zhengzhou 450001, Peoples R China
基金
美国国家科学基金会;
关键词
Magnetite; Pentlandite; Serpentine; Magnetic coating; NICKEL ORE; FLOTATION; SEPARATION; MINERALS; DEPRESSION; MECHANISMS; LIZARDITE; RECOVERY; QUARTZ; TALC;
D O I
10.1016/j.mineng.2014.12.038
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The effects of magnetite as the magnetic seed on magnetic coating behavior in pentlandite and serpentine system were investigated through magnetic separation tests, X-ray diffraction analysis, zeta potential measurements, and calculations of DLVO (Derjaguin-Landau-Verwey-Overbeek) theory. The results show that, the pentlandite recovery increased with the increment of magnetite while the recovery of serpentine remained low. Results obtained from XRD indicate that magnetite adhered predominately to the surface of pentlandite but only marginally to serpentine. Zeta potential measurements demonstrate that at pH values above 4.0, surfaces of serpentine, magnetite and pentlandite were all negatively charged with the sodium hexametaphosphate (SHMP) addition, and the serpentine with a higher negative potential surface following by magnetite and pentlandite. Thus, the repulsive force between pentlandite and serpentine was stronger, which weakens the hetero-aggregation between them. Calculations of DLVO theory indicate that the interaction energy between magnetite and pentlandite particles was higher than that between magnetite and serpentine. Consequently, it was easier for fine magnetite fractions to adhere to the surface of pentlandite particles and enhances its magnetism to allow for the magnetic separation of pentlandite from serpentine. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码:115 / 120
页数:6
相关论文
共 18 条
[1]   Separation of fine mineral particles by selective magnetic coating [J].
Anastassakis, GN .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2002, 256 (01) :114-120
[2]   The effect of polysaccharides and polyacrylamides on the depression of talc and the flotation of sulphide minerals [J].
Beattie, DA ;
Huynh, L ;
Kaggwa, GBN ;
Ralston, J .
MINERALS ENGINEERING, 2006, 19 (6-8) :598-608
[3]   Pentlandite-lizardite interactions and implications for their separation by flotation [J].
Bremmell, KE ;
Fornasiero, D ;
Ralston, J .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2005, 252 (2-3) :207-212
[4]   The effect of high intensity conditioning on the flotation of a nickel ore, part 2: Mechanisms [J].
Chen, G ;
Grano, S ;
Sobieraj, S ;
Ralston, J .
MINERALS ENGINEERING, 1999, 12 (11) :1359-1373
[5]  
Edwards G.R., 1980, INT J MINER PROCESS, V7, P33
[6]  
[冯博 Feng Bo], 2013, [中南大学学报. 自然科学版, Journal of Central South University of Science and Technology], V44, P2644
[7]   Talc-serpentine interactions and implications for talc depression [J].
Feng, Bo ;
Lu, Yiping ;
Feng, Qiming ;
Zhang, Mingyang ;
Gu, Yanling .
MINERALS ENGINEERING, 2012, 32 :68-73
[8]   Cu(II) and Ni(II) activation in the flotation of quartz, lizardite and chlorite [J].
Fornasiero, D ;
Ralston, J .
INTERNATIONAL JOURNAL OF MINERAL PROCESSING, 2005, 76 (1-2) :75-81
[9]  
He H.H., 2004, NI CO METALLURGY CHI
[10]   Magnetic separation of ferrihydrite from wastewater by magnetic seeding and high-gradient magnetic separation [J].
Karapinar, N .
INTERNATIONAL JOURNAL OF MINERAL PROCESSING, 2003, 71 (1-4) :45-54