Photoinduced electron transfer in porphyrin-quinone cyclophanes, 16 - Distance dependence of photoinduced electron transfer: Syntheses and properties of anthracene-spacered porphyrin-quinone cyclophanes

被引：0

作者：

Staab, HA ^{[1
]}

Hauck, R ^{[1
]}

Popp, B ^{[1
]}

机构：

[1] Max Planck Inst Med Res, Arbeitsgrp Organ Chem, D-69120 Heidelberg, Germany

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 1998年 / 1998卷 / 04期

关键词：

electron transfer; distance dependence of; anthracene-spacered porphyrin-quinone cyclophanes; syntheses; characterizations; structures; physical properties;

D O I：

10.1002/(SICI)1099-0690(199804)1998:4<631::AID-EJOC631>3.0.CO;2-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In our previous work on benzene-and naphthalene-spacered porphyrin-quinone cyclophanes([1][2]), the dependence of electron-transfer rates on reduction potentials of the acceptors and oxidation potentials of the porphyrins was studied. The present paper, dealing with the distance dependence of electron transfer, reports on the synthesis of anthracene-spacered analogues and on the electron-transfer rates, which are found to be drastically reduced.

引用

页码：631 / 642

页数：12

共 22 条

[1] A NEW SYNTHESIS OF PYRROLES FROM NITROALKENES [J].

BARTON, DHR ;

ZARD, SZ .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (16) :1098-1100

[2]

DERNBACH M, 1993, THESIS U HEIDELBERG

[3]

FRANK M, 1995, THESIS U HEIDELBERG

[4] Ultrafast charge separation and driving force dependence in cyclophane-bridged Zn-porphyrin-quinone molecules [J].

Haberle, T ;

Hirsch, J ;

Pollinger, F ;

Heitele, H ;

MichelBeyerle, ME ;

Anders, C ;

Dohling, A ;

Krieger, C ;

Ruckemann, A ;

Staab, HA .

JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (46) :18269-18274

[5] THE BEHAVIOR OF 3-CHLOROPHTHALIC ANHYDRIDE IN FRIEDEL-CRAFTS AND GRIGNARD CONDENSATIONS [J].

NEWMAN, MS ;

SCHEURER, PG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1956, 78 (19) :5004-5007

[6]

Pollinger F, 1996, BER BUNSEN PHYS CHEM, V100, P2076

[7]

Staab H. A., 1994, ANGEW CHEM, V106, P2542

[8] PHOTOINDUCED ELECTRON TRANSFER IN PORPHYRIN-QUINONE CYCLOPHANES .10. ZINC COMPLEXES OF PORPHYRIN-QUINONE CYCLOPHANES - SYNTHESES, STRUCTURES, AND ELECTRON-TRANSFER-RELATED-PROPERTIES [J].

STAAB, HA ;

KRIEGER, C ;

ANDERS, C ;

RUCKEMANN, A .

CHEMISCHE BERICHTE, 1994, 127 (01) :231-236

[9]

Staab HA, 1997, LIEBIGS ANN-RECL, P2321

[10] PORPHYRIN-QUINONE CYCLOPHANES WITH GRADUALLY VARIED ACCEPTOR STRENGTH - SYNTHESES AND CHARACTERIZATIONS [J].

STAAB, HA ;

WEISER, J ;

FUTSCHER, M ;

VOIT, G ;

RUCKEMANN, A ;

ANDERS, C .

CHEMISCHE BERICHTE-RECUEIL, 1992, 125 (10) :2285-2301

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