The new lead-free ferroelectrics with composition of 0.995[(K0.5Na0.5)(0.95)Li-0.05](Nb0.95Sb0.05)O-3-0.005BaTiO(3) (0.995KNLNS-0.005BT) were prepared by using normal sintering method, and the ferroelectric relaxor behavior and electrical properties of the ceramics were systematically studied. The ceramics exhibit typical ferroelectric relaxor behavior, that is, the dielectric peaks become increasingly broad, and the temperature of the maximum dielectric constant is shifted to higher temperature with the increasing frequency. The dielectric relaxor behavior follows the modified Curie Weiss law. The relaxor behavior of the ceramics should be attributed to the cationic disorder induced by both of the A-sites and B-sites substitutions. The 0.995KNLNS-0.005BT ceramics also exhibit good piezoelectric properties with d(33) of 269 pC/N, k(p) of 0.50, epsilon(r) of 1371, tan delta of 0.03, T-C of 349 degrees C, P-r of 22.4 mu C/cm(2), and E-c=15.3 kV/cm.
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Korea Inst Sci & Technol, Elect Mat Res Ctr, Seoul 136791, South Korea
Univ Maryland, Inst Res Elect & Appl Phys, College Pk, MD 20742 USAKorea Inst Sci & Technol, Elect Mat Res Ctr, Seoul 136791, South Korea
Ha, Jong-Yoon
Choi, Ji-Won
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Korea Inst Sci & Technol, Elect Mat Res Ctr, Seoul 136791, South KoreaKorea Inst Sci & Technol, Elect Mat Res Ctr, Seoul 136791, South Korea
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Lanzhou Univ Technol, Sch Mat Sci & Engn, State Key Lab Adv Proc & Recycling Nonferrous Met, Lanzhou 730050, Peoples R ChinaLanzhou Univ Technol, Sch Mat Sci & Engn, State Key Lab Adv Proc & Recycling Nonferrous Met, Lanzhou 730050, Peoples R China
Yan, Xiaobin
Peng, Biaolin
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Hong Kong Polytech Univ, Dept Appl Phys, Kowloon, Hong Kong, Peoples R ChinaLanzhou Univ Technol, Sch Mat Sci & Engn, State Key Lab Adv Proc & Recycling Nonferrous Met, Lanzhou 730050, Peoples R China
Peng, Biaolin
Lu, Xuefeng
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Lanzhou Univ Technol, Sch Mat Sci & Engn, State Key Lab Adv Proc & Recycling Nonferrous Met, Lanzhou 730050, Peoples R ChinaLanzhou Univ Technol, Sch Mat Sci & Engn, State Key Lab Adv Proc & Recycling Nonferrous Met, Lanzhou 730050, Peoples R China
Lu, Xuefeng
Dong, Qizheng
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Lanzhou Univ Technol, Sch Mat Sci & Engn, State Key Lab Adv Proc & Recycling Nonferrous Met, Lanzhou 730050, Peoples R ChinaLanzhou Univ Technol, Sch Mat Sci & Engn, State Key Lab Adv Proc & Recycling Nonferrous Met, Lanzhou 730050, Peoples R China
Dong, Qizheng
Li, Wensheng
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Lanzhou Univ Technol, Sch Mat Sci & Engn, State Key Lab Adv Proc & Recycling Nonferrous Met, Lanzhou 730050, Peoples R ChinaLanzhou Univ Technol, Sch Mat Sci & Engn, State Key Lab Adv Proc & Recycling Nonferrous Met, Lanzhou 730050, Peoples R China
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Anhui Univ, Sch Phys & Mat Sci, Hefei 230601, Peoples R China
Anhui Univ, Dept Chem & Mat Engn, Hefei 230601, Peoples R ChinaAnhui Univ, Sch Phys & Mat Sci, Hefei 230601, Peoples R China
Yin, Qiyi
Sun, Zhaoqi
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Anhui Univ, Sch Phys & Mat Sci, Hefei 230601, Peoples R ChinaAnhui Univ, Sch Phys & Mat Sci, Hefei 230601, Peoples R China
Sun, Zhaoqi
Zhang, Miao
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Anhui Univ, Sch Phys & Mat Sci, Hefei 230601, Peoples R ChinaAnhui Univ, Sch Phys & Mat Sci, Hefei 230601, Peoples R China
Zhang, Miao
He, Gang
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Anhui Univ, Sch Phys & Mat Sci, Hefei 230601, Peoples R ChinaAnhui Univ, Sch Phys & Mat Sci, Hefei 230601, Peoples R China
He, Gang
Chen, Yang
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Anhui Univ, Dept Chem & Mat Engn, Hefei 230601, Peoples R ChinaAnhui Univ, Sch Phys & Mat Sci, Hefei 230601, Peoples R China
Chen, Yang
Wang, Qing
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Anhui Univ, Dept Chem & Mat Engn, Hefei 230601, Peoples R ChinaAnhui Univ, Sch Phys & Mat Sci, Hefei 230601, Peoples R China
Wang, Qing
Yan, Mingzhu
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Anhui Univ, Dept Chem & Mat Engn, Hefei 230601, Peoples R ChinaAnhui Univ, Sch Phys & Mat Sci, Hefei 230601, Peoples R China