Synthesis and crystal structure of anionic zirconium (II) intermediate for carbon-carbon coupling:: Li[Cp2Zr(C≡CPh)(η2: 1,2-PhC2C≡CPh)]

被引：0

作者：

Zhao, JS ^{[1
]}

Gu, AP

He, SY

Robert, C

Lydie, V

Patrick, C

机构：

[1] NW Univ Xian, Shaanxi Key Lab Physicoinorgan Chem, Dept Chem, Xian 710069, Peoples R China

[2] CNRS, Chim Coordinat Lab, F-31077 Toulouse, France

来源：

CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE | 2003年 / 24卷 / 04期

关键词：

C-C coupling; anionic zirconium(II) intermediate; synthesis; crystal structure;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The unexpected anionic Zr (II) complex [Cp2Zr(CdropCPh) (eta(2):1, 2-PhC(2)CdropCPh)](-) was isolated from LiCdropCPh and Cp2ZrCl2 in THF, giving clear, evidce for a C-C coupling between two alkynyl moieties, one of them being eta(2)-bonded to the zirconium atom. The complex was characterized by elemental analysis, NMR, IR spectroscopy and X-ray diffraction. The synthesis reaction mechanism was discussed.

引用

页码：580 / 583

页数：4

共 19 条

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