Synthesis, structural characterization of a novel 4,4′-bipyridyl based HgI2 adduct

被引：16
作者：
Niu, YY
Zheng, HG [1 ]
Fun, H
Razak, IA
Chantrapromma, S
Xin, XQ
机构：
[1] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
[2] Zhengzhou Univ, Dept Chem, Zhengzhou 450052, Peoples R China
[3] Univ Sains Malaysia, Sch Phys, Xray Crystallog Unit, George Town, Malaysia
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 2003年 / 33卷 / 01期
基金：
美国国家科学基金会;
关键词：
mercury iodide; polymer adduct; 4,4-bipyridine; zigzag structure;
D O I：
10.1081/SIM-120016868
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel mercury iodide adduct, [HgI2(4,4'-bipy)], was synthesized by the reaction of HgI2 with 4,4'-bipyridine in THF. The structure characterization was performed by means of. IR, elemental analyses and single crystal X-ray analysis. The structure of [HgI2(4,4'-bipy)](n) consists of distorted tetrahedral Hg(II) centers bridged by 4,4'-bipy ligands to form one-dimensional zigzag chains without iodide bridging.
引用
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页码：1 / 10
页数：10
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