Polytriazole/clay nanocomposites synthesized using in situ polymerization and click chemistry

被引：36

作者：

Ye, Yun-Sheng ^{[1
]}

Yen, Ying-Chieh ^{[1
]}

Cheng, Chih-Chia ^{[1
]}

Syu, Yu-Jyuan ^{[1
]}

Huang, Yao-Jeng ^{[1
]}

Chang, Feng-Chih ^{[1
]}

机构：

[1] Natl Chiao Tung Univ, Inst Appl Chem, Hsinchu 30050, Taiwan

来源：

POLYMER | 2010年 / 51卷 / 02期

关键词：

Clay; In situ polymerization; Click chemistry; 1,3-DIPOLAR CYCLOADDITION; POLYIMIDE NANOCOMPOSITES; RADICAL POLYMERIZATION; BLOCK-COPOLYMERS; CLAY; POLYSTYRENE; MONTMORILLONITE; AZIDES; GENERATION; LIGATION;

D O I：

10.1016/j.polymer.2009.11.015

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

This manuscript describes the preparation of polytriazole/clay nanocomposites through in situ polymerization of PTA, using click chemistry, in the presence of a propargyl-modified clay. The clay layers became exfoliated and dispersed well in the PTA matrix, thereby improving the thermal and mechanical properties of the clay. This approach can be extended to combine propargyl-modified clays with other azide- and alkyne-containing polymers. (C) 2009 Elsevier Ltd. All rights reserved.

引用

页码：430 / 436

页数：7

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