Recent progress in transition-metal-catalyzed trifluoromethylation of olefins using electrophilic CF3 reagents

被引：81

作者：

Koike, Takashi ^{[1
]}

Akita, Munetaka ^{[1
]}

机构：

[1] Tokyo Inst Technol, Chem Resources Lab, Tokyo, Japan

来源：

JOURNAL OF FLUORINE CHEMISTRY | 2014年 / 167卷

关键词：

Trifluoromethylation; Transition metal catalyst; Alkene difunctionlalization; Electrophilic CF3 reagent; Photocatalysis; Step economy; BOND FORMATION; 3-COMPONENT OXYTRIFLUOROMETHYLATION; ASYMMETRIC FLUORINATION; UNACTIVATED ALKENES; TERMINAL ALKENES; COPPER; PHOTOREDOX; CONSTRUCTION; EFFICIENT; HYDROTRIFLUOROMETHYLATION;

D O I：

10.1016/j.jfluchem.2014.06.025

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

For the past few years, transition-metal-catalyzed trifluoromethylation of olefins has been rapidly developing and has provided various types of organofluorine compounds containing a C(sp(3))-CF3 bond. In this review, we will concisely summarize recent development of trifluoromethylation of C=C bonds effected by a combination of transition metal catalysis and electrophilic trifluoromethylating reagents, such as Umemoto's and Togni's reagents. (C) 2014 Elsevier B.V. All rights reserved.

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页码：30 / 36

页数：7

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