Heat capacities of polycrystalline nLiH and nLiD by differential scanning calorimetric method

被引：7

作者：

Jat, Ram Avtar ^{[1
]}

Parida, S. C. ^{[1
]}

Krishnan, K. ^{[2
]}

Anand, N. S. ^{[1
]}

Sawant, S. G. ^{[1
]}

Agarwal, Renu ^{[1
]}

Singh, Ziley ^{[1
]}

Aggarwal, S. K. ^{[2
]}

Venugopal, V. ^{[3
]}

机构：

[1] Bhabha Atom Res Ctr, Product Dev Div, Bombay 400085, Maharashtra, India

[2] Bhabha Atom Res Ctr, Div Fuel Chem, Bombay 400085, Maharashtra, India

[3] Bhabha Atom Res Ctr, RC&I Grp, Bombay 400085, Maharashtra, India

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 2010年 / 505卷 / 01期

关键词：

Lithium hydride; Heat capacity; Differential scanning calorimetry; Thermodynamic functions; Isotopic effect; EQUATION-OF-STATE; THERMAL-EXPANSION; LITHIUM HYDRIDE; LATTICE-DYNAMICS; THERMODYNAMIC PROPERTIES; LIH; ISOTOPE; DIFFRACTION; PRESSURE;

D O I：

10.1016/j.jallcom.2010.06.059

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The heat capacities of polycrystalline (LiH)-Li-n and (LiD)-Li-n were measured by differential scanning calorimeter in the temperature range from 125 to 800K. The smoothed values of heat capacities were used to calculate various thermodynamic functions for (LiH)-Li-n and (LID)-L-n from 0 to 800K. Isotopic effect on heat capacity of (LiH)-Li-n and (LiD)-Li-n is predominant at higher temperatures (>80 K) whereas below 80K the isotopic effect is negligible. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：309 / 314

页数：6

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