Features of Hydrolysis of Concentrated Aqueous Alkaline Solutions of NaBH4 on Co/TiO2 Catalyst

被引：1

作者：

Shabunya, S., I ^{[1
]}

Minkina, V. G. ^{[1
]}

Kalinin, V., I ^{[1
]}

机构：

[1] Natl Acad Sci Belarus, Luikov Heat & Mass Transfer Inst, Minsk 220072, BELARUS

来源：

KINETICS AND CATALYSIS | 2022年 / 63卷 / 05期

关键词：

sodium borohydride; catalytic hydrolysis; cobalt; schemes of sorption and kinetic processes; HYDROGEN GENERATION; SODIUM-BOROHYDRIDE; B CATALYST; KINETICS; OXIDE;

D O I：

10.1134/S002315842205010X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Kinetic experiments were carried out on the hydrolysis of concentrated aqueous and aqueous alkaline solutions of NaBH4 with a Co/TiO2 catalyst. The experiments in the aqueous NaBH4 solutions were performed at molal concentrations of 0.25, 1, and 4 mol/kg. In the aqueous alkaline solutions with molal NaBH4 concentrations of 0.25 and 1 mol/kg, the molal NaOH concentrations were varied in the range 0.05-8 mol/kg. The activation energies in the aqueous solution and the aqueous alkaline solutions were found to be 64.3 and 53.6 kJ/mol, respectively. Features of the kinetic curves and the possible kinetic schemes were discussed.

引用

页码：585 / 592

页数：8

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