Nucleophilic addition of alcohols to the C-N multiple bonds of the nitrilium substituent in the anion [2-B10H9(Naparts per thousandCMe)]-

被引：25

作者：

Zhdanov, A. P. ^{[1
]}

Lisovsky, M. V. ^{[1
]}

Goeva, L. V. ^{[1
]}

Razgonyaeva, G. A. ^{[1
]}

Polyakova, I. N. ^{[1
]}

Zhizhin, K. Yu. ^{[1
]}

Kuznetsov, N. T. ^{[1
]}

机构：

[1] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 119991, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2009年 / 58卷 / 08期

基金：

俄罗斯基础研究基金会;

关键词：

organoboranes; boron-containing cluster anions; addition to carbon-nitrogen multiple bonds; NEUTRON-CAPTURE THERAPY; CHEMISTRY;

D O I：

10.1007/s11172-009-0234-9

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reactions of salts of the anion [2-B10H9(Na parts per thousand CMe)](-) with aliphatic alcohols ROH (R = C (n) H2n+1 (n = 1-6) CH2CH2(OEt), Pr-i, Bu-i, Bu-t, i-C5H11) are studied. These reactions result in hydrolytically stable imidates [2-B10H9{NH=C(OR)Me}](-). Their structures were confirmed by the data from mass spectrometry, IR, H-1, B-11, and C-13 NMR spectroscopy. The molecular geometry of [2(Z)-B10H9{NH=C(OBu)Me}](-), which formed in nucleophilic addition reaction of n-butyl alcohol to [2-B10H9(Na parts per thousand CMe)](-), was established by X-ray diffraction analysis.

引用

页码：1694 / 1700

页数：7

共 12 条

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