Catalysts with Pt Surface Coating by Atomic Layer Deposition for Solid Oxide Fuel Cells

被引:40
作者
Shim, Joon Hyung [1 ]
Jiang, Xirong [2 ]
Bent, Stacey F. [3 ]
Prinz, Fritz B. [4 ,5 ]
机构
[1] Korea Univ, Dept Mech Engn, Seoul 136701, South Korea
[2] Stanford Univ, Dept Phys, Stanford, CA 94305 USA
[3] Stanford Univ, Dept Chem Engn, Stanford, CA 94305 USA
[4] Stanford Univ, Dept Mech Engn, Stanford, CA 94305 USA
[5] Stanford Univ, Dept Mat Sci & Engn, Stanford, CA 94305 USA
关键词
YTTRIA-STABILIZED ZIRCONIA; RUTHENIUM NANOPARTICLES; ELECTRONIC-STRUCTURE; HIGH-PERFORMANCE; X-RAY; PLATINUM; TEMPERATURE; SILVER; OXYGEN; XPS;
D O I
10.1149/1.3368787
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
We tested the atomic layer deposition of platinum layers onto various sputtered porous metals including silver, palladium, ruthenium, and gold as catalysts for solid oxide fuel cells. We investigated thermal and chemical stability against oxidation using X-ray photoelectron spectroscopy. Fuel cell tests were conducted using the metal-atomic layer deposition platinum cathodes with 200 mu m thick, 8% yttria-stabilized zirconia electrolytes and sputtered platinum anodes. Performance of the fuel cells was measured by comparing the current-voltage curves and maximum power densities with varying temperature. (C) 2010 The Electrochemical Society. [DOI: 10.1149/1.3368787] All rights reserved.
引用
收藏
页码:B793 / B797
页数:5
相关论文
共 29 条
[1]   Atomic layer deposition of platinum thin films [J].
Aaltonen, T ;
Ritala, M ;
Sajavaara, T ;
Keinonen, J ;
Leskelä, M .
CHEMISTRY OF MATERIALS, 2003, 15 (09) :1924-1928
[2]   Interaction of oxygen with silver at high temperature and atmospheric pressure: A spectroscopic and structural analysis of a strongly bound surface species [J].
Bao, X ;
Muhler, M ;
SchedelNiedrig, T ;
Schlogl, R .
PHYSICAL REVIEW B, 1996, 54 (03) :2249-2262
[3]   Growth and structure of silver and silver oxide thin films on sapphire [J].
Bock, FX ;
Christensen, TM ;
Rivers, SB ;
Doucette, LD ;
Lad, RJ .
THIN SOLID FILMS, 2004, 468 (1-2) :57-64
[4]   PLASMA-INDUCED OXIDATION OF AG(110) [J].
BOWKER, M .
SURFACE SCIENCE, 1985, 155 (2-3) :L276-L280
[5]   Theoretical analysis of reactivity on Pt(111) and Pt-Pd(111) alloys [J].
Calvo, Sergio R. ;
Balbuena, Perla B. .
SURFACE SCIENCE, 2007, 601 (21) :4786-4792
[6]   Acetate- and thiol-capped monodisperse ruthenium nanoparticles:: XPS, XAS, and HRTEM studies [J].
Chakroune, N ;
Viau, G ;
Ammar, S ;
Poul, L ;
Veautier, D ;
Chehimi, MM ;
Mangeney, C ;
Villain, F ;
Fiévet, F .
LANGMUIR, 2005, 21 (15) :6788-6796
[7]   Synthesis and characterization of nano-sized gold-palladium bimetallic particles dispersed in polymer thin film matrix [J].
Deki, S ;
Akamatsu, K ;
Hatakenaka, Y ;
Mizuhata, M ;
Kajinami, A .
NANOSTRUCTURED MATERIALS, 1999, 11 (01) :59-65
[8]   Thin-film solid oxide fuel cell with high performance at low-temperature [J].
deSouza, S ;
Visco, SJ ;
DeJonghe, LC .
SOLID STATE IONICS, 1997, 98 (1-2) :57-61
[9]   Development of solid-oxide fuel cells that operate at 500°C [J].
Doshi, R ;
Richards, VL ;
Carter, JD ;
Wang, XP ;
Krumpelt, M .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1999, 146 (04) :1273-1278
[10]   ELECTRONIC-STRUCTURE OF ALUMINUM AND ALUMINUM-NOBLE-METAL ALLOYS STUDIED BY SOFT-X-RAY AND X-RAY PHOTOELECTRON SPECTROSCOPIES [J].
FUGGLE, JC ;
KALLNE, E ;
WATSON, LM ;
FABIAN, DJ .
PHYSICAL REVIEW B, 1977, 16 (02) :750-761